| Round 5 | | Leeds United | 1 | 77 Vinícius Júnior | | Half-time: | 0-0 | | Referee: | Laws 7 | | Attendance: | 37,877 | | Possession: | 52%-48% | | Total shots: | 21-15 | | MoM: | Tagliafico |
| | 39 Dumfries | | (3-5-2): Nübel 7½, Di Lorenzo 6½, Tagliafico 8, Zubimendi 7, Natan 7, Bruno Guimarães 7½, Dumfries 7, Asensio 8, Vinícius Júnior 7, Giroud 7, Saúl 6 | | Aston Villa | 0 |
| | 79 Fabián | | (4-3-3): Martínez 8, Pedro Porro 7, Hernández 7, Rabiot 7, Romero 7½, Laporte 6, Zaniolo 7, Di María 6½, Lazetic 6, Fabián 6½, Torres 7 (70 Depay 6) | | Port Vale | 2 | 6 Trossard, 10 Sarr | | Half-time: | 2-1 | | Referee: | Drysdale 7 | | Attendance: | 18,983 | | Possession: | 44%-56% | | Total shots: | 6-15 | | MoM: | Rúben Dias | | TV: | highlights |
| | 18 Mitoma, 19 Sarr | | (4-1-3-2): Benítez 6½, Ryerson 6½, Udogie 8, Bremer 6½, White 6½, Sarr 7, Mudryk 7, Mitoma 6½, Gouiri 7, Müller 7, Trossard 7 | | Manchester City | 2 | 44 Foden, 73 Messi |
| | (3-4-3): Donnarumma 6, Bellingham 6½, Rúben Dias 8, Saka 6, De Bruyne 6½, Rodri 7½, Varane 6½, Davies 7, Foden 6½, Haaland 6, Messi 7½ |
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