| League Cup results | | Round 3 | | Oldham Athletic | 0-2 | Millwall | | |
| 271(p) | Weghorst | | |
| 442(p) | Weghorst | | WBA | 1-3 | Manchester United | | 402 | Fellows |
| 121(og) | João Mário | | |
| 161 | Vinícius Júnior | | |
| 212 | Vinícius Júnior | | Colchester United | 4-0 | Barnsley | | 311 | Giroud |
| | | | 331 | Giroud |
| | | | 72 | Giroud |
| | | | 422 | Giroud |
| | | | Leicester City | 5-0 | AFC Wimbledon | | 341 | Watkins |
| | | | 22 | Rodrygo |
| | | | 272 | Rodrygo |
| | | | 312 | Díaz |
| | | | 362 | Díaz |
| | | | Carlisle United | 1-2 | Brentford | | 121 | Ivan Cavaleiro |
| 291 | Joelinton | | |
| 73 | Bech | | West Ham United | 0-2 | Barnet | | |
| 261 | Sané | | |
| 202 | Marcos Llorente | | Liverpool | 1-2 | Cardiff City | | 341 | Terrier |
| 261 | Udogie | | |
| 342 | Yamal | | Tottenham Hotspur | 1-3 | Wolves | | 161 | Cornet |
| 211(og) | Carter-Vickers | | |
| 182 | Origi | | |
| 392 | Stiller | | |
| 402 |  João Moutinho | | Manchester City | 0-0 | Mansfield Town | | Stockport County | 2-0 | Chelsea | | 191 | Son |
| | | | 401 | Son |
| | | | Boston United | 2-1 | Darlington | | 62 | Mejbri |
| 31 | Dobre | | 152 | Mejbri |
| | | | Chester | 1-1 | Cambridge United | | 161 | Thiago Heleno |
| 212 | Ekuban | | Plymouth Argyle | 3-1 | Burnley | | 11 | Scamacca |
| 402 | Collins | | 272 | Tadic |
| | | | 342 | Tadic |
| | | | Lincoln City | 0-2 | Aston Villa | | |
| 291 | Martinelli | | |
| 402 | Immobile | | Cheltenham Town | 3-1 | Leeds United | | 311 | Roberto Firmino |
| 101 | Harrison | | 431 | Roberto Firmino |
| | | | 422(p) | Roberto Firmino |
| | | | Wrexham | 2-0 | Walsall | | 101 | Sakamoto |
| | | | 342 | Sakamoto |
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