| Round 3 | | Ajax | 1 | 22 Schřne | | Half-time: | 1-2 | | Referee: | Pyanikh 6½ | | Attendance: | 32,571 | | Possession: | 35%-65% | | Total shots: | 8-19 | | MoM: | Dante |
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| | (4-3-3): Van Der Hart 6½, Martina 6, Kishna 6, Moisander 7, Denswil 6, Van Der Hoorn 6, Duarte 6, Schřne 6½, Milik 6½, Sigţórsson 5½, Bojan 6 | | Botafogo | 2 | 12 Vitinho, 20 Michel Bastos |
| | (4-3-3): Jéfferson 7, Fabinho 8, Laxalt 7 (81 Gabriel 7½), Paulinho 8, Dante 9, Mário Fernandes 6½, Leandrinho 7½, Michel Bastos 7 (55 Rodrigo Caio 7½), Vitinho 7½, Pasalic 6½, Ronaldinho 7 | | Arsenal | 2 | 13 Campbell, 43 Walcott | | Half-time: | 2-1 | | Referee: | Levnikov 6½ | | Attendance: | 52,280 | | Possession: | 56%-44% | | Total shots: | 15-8 | | MoM: | Kolasinac |
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| | (4-3-3): Ospina 7, Bellerín 7½, Nacho Monreal 8, Santi Cazorla 6½, Chambers 7½, Gibbs 7½, Walcott 6½, Sánchez 7½, Campbell 7½, Oxlade-Chamberlain 6, Welbeck 6½ | | Hertha BSC Berlin | 1 | 37p Aubameyang |
| | (4-3-3): Adler 6½, Schwaab 7, Kolasinac 8, Niemeyer 6, Brooks 6½, Hubník 6, Olkowski 6½ (71 Pohjanpalo 6), Mukhtar 7, Aubameyang 6½, Kalou 5½, Gerard 6 | | Baník Ostrava | 2 | 26 Promes, 77 Martial | | Half-time: | 1-1 | | Referee: | Huzu 5½ | | Attendance: | 17,231 | | Possession: | 51%-49% | | Total shots: | 8-12 | | MoM: | Borja Bastón |
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| | (4-3-3): Nyland 7, Fornasier 7½, Aké 6½, Oliver 6 (69 Borja Bastón 8), Naldo 6½, Balanta 7, Promes 7½, Martial 7, Córdoba 6, Sanson 6, Baldé 6 | | Monaco | 2 | 43 Mendy, 87p Touré | | 34 Ndinga | | (4-3-3): De Ruiter 6½, Appiah 7½, Kurzawa 6½, Toulalan 6½ (66 Coulibaly 7), Medjani 7, Sidibé 6½, Mendy 6, Alessandrini 7, Touré 7, Ndinga 6, Germain 6½ | | New York | 0 |
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| | (4-3-3): Krul 6½, Kühne 7, Johnson 7, Nainggolan 8, Gabriel Paulista 6½, Wanyama 6½, Giovani 7, Parolo 7½, Altidore 6, Cook 6, Benayoun 6 | | Pescara | 1 | 3 Mandzukic |
| | (4-3-3): Consigli 6½, Rüdiger 6½, Vertonghen 7, Soriano 7, Otamendi 6½, Jantschke 6, Montolivo 6½, Mandzukic 7, Belotti 6, Bender 6, Çelik 6½ | | Parma | 3 | 12 Perotti, 15 Rispoli, 43 Acquah | | Half-time: | 3-0 | | Referee: | Uilenberg 6½ | | Attendance: | 27,752 | | Possession: | 57%-43% | | Total shots: | 14-12 | | MoM: | Perotti |
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| | (4-3-3): Mirante 7½, Pedro Mendes 7, Peluso 7, Acquah 7½, Paletta 5½ (81 Biabiany 6), Felipe 6½, Rispoli 7, Perotti 8, Belfodil 6½, Jorquera 6, Palladino 6½ | | Anzhi | 0 |
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| | (4-3-3): Buffon 7½, Jedvaj 7, Zhirkov 7 (55 Januzaj 6½), Onazi 7½, Piqué 6½, Thiago Silva 7, Ramires 7 (80 Garay 6), Mkhitaryan 6½, Balotelli 7, Boussoufa 6, Lavezzi 5½ | | Round 4 | | América | 0 |
| | Half-time: | 0-1 | | Referee: | Craciun 6 | | Attendance: | 42,485 | | Possession: | 44%-56% | | Total shots: | 16-14 | | MoM: | Coman |
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| | (4-3-3): Marchesín 6, Salcedo 7½, Cáceres 6, Bermúdez 7½, Reyes 6½, Maza 7, Dos Santos 6½, Rodríguez 7, Peralta 7, Atsu 7 (60 Coulibaly 6), Iago 6 | | Bayern München | 1 | 3 Coman |
| | (4-3-3): Neuer 7, Kimmich 7½, Bernat 6, Götze 7½, Boateng 7, McShane 6, Coman 8, Douglas Costa 7, Aitchison 6½, Green 6, Müller 6½ | | Botafogo | 1 | 40og Nacho Monreal | | Half-time: | 1-1 | | Referee: | Reijgwart 6½ | | Attendance: | 42,040 | | Possession: | 48%-52% | | Total shots: | 10-17 | | MoM: | Laxalt |
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| | (4-3-3): Jéfferson 7, Fabinho 6, Laxalt 8, Paulinho 7½, Dante 6½, Mário Fernandes 6, Leandrinho 6, Michel Bastos 6½, Vitinho 6½, Pasalic 6½, Ronaldinho 7 | | Arsenal | 1 | 6 Sánchez |
| | (4-3-3): Ospina 7, Bellerín 6½, Nacho Monreal 6½ (63 Coquelin 7½), Santi Cazorla 7½, Chambers 7, Gibbs 7½, Walcott 6½, Sánchez 7½, Campbell 6½, Oxlade-Chamberlain 6½, Welbeck 6½ | | Caen | 1 | 17 Adéoti | | Half-time: | 1-1 | | Referee: | McCluskey 6 | | Attendance: | 20,848 | | Possession: | 54%-46% | | Total shots: | 17-17 | | MoM: | Sesták |
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| | (4-3-3): Vercoutre 6½, Dabo 7, Bessat 7, Féret 7, Da Silva 6½, Genevois 6, Delaplace 7, Imorou 7, Santini 7, Adéoti 6½, Rodelin 6½ | | TSV München 1860 | 1 | 14 Denis |
| | (4-3-3): Pletikosa 5½, Schindler 5½, Bekir 6, Sheshukov 7, Stranzl 6½, Richards 6, Aigner 6, Denis 6, Sesták 7½, Hofmann 6, Wood 6½ | | Hertha BSC Berlin | 3 | 4 Aubameyang, 61 Kolasinac, 65 Olkowski | | Half-time: | 1-0 | | Referee: | Dinelli 7 | | Attendance: | 40,424 | | Possession: | 55%-45% | | Total shots: | 13-6 | | MoM: | Peluso | | TV: | live |
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| | (4-3-3): Adler 7, Schwaab 6½, Kolasinac 7½, Niemeyer 7½, Brooks 7, Hubník 7, Olkowski 5½ (83 Pohjanpalo 6), Mukhtar 7, Aubameyang 7½, Kalou 5½, Gerard 6 | | Parma | 0 |
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| | (4-3-3): Mirante 7, Pedro Mendes 6, Peluso 8, Acquah 7, Paletta 8, Felipe 6, Rispoli 7, Perotti 7½, Belfodil 7, Jorquera 6½, Palladino 6 | | Monaco | 3 | 26 Ndinga, 73 Germain, 82p Touré | | Half-time: | 1-1 | | Referee: | Díaz Vega 6½ | | Attendance: | 18,461 | | Possession: | 60%-40% | | Total shots: | 14-8 | | MoM: | Ndinga | | TV: | highlights |
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| | (4-3-3): De Ruiter 7½, Appiah 6½, Kurzawa 7½, Toulalan 5½ (66 Coulibaly 7½), Medjani 7½, Sidibé 7, Mendy 7½, Alessandrini 7, Touré 7½, Ndinga 7½, Germain 6½ | | Newell's Old Boys | 1 | 36 Ramsey |
| | (4-3-3): Aitor 6½, Ginter 6½, Schmelzer 7, Ramsey 7 (73 López 6), Martínez 6½, Terry 6, Cabaye 6½, Pastore 6½, Drogba 6 (78 Adriano 6½), Rodríguez 6½, Kokorin 6 | | Pescara | 3 | 59 Belotti, 65 Montolivo, 87 Mandzukic | | Half-time: | 0-2 | | Referee: | Young 7 | | Attendance: | 20,596 | | Possession: | 54%-46% | | Total shots: | 12-9 | | MoM: | Vertonghen | | TV: | highlights |
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| | (4-3-3): Consigli 6, Rüdiger 7½, Vertonghen 8, Soriano 6½, Otamendi 5½ (62 Cosic 7), Jantschke 7½, Inler 7, Mandzukic 7, Belotti 7½, Montolivo 7, Çelik 5½ | | Rangers | 2 | 17 Sanabria, 35 Sanabria |
| | (4-3-3): Kaminski 6½, Stones 6½, Mendy 7½, Thiago 7, Ceccherini 6½, Murru 7 (72 Milito 6), Gündogan 6, Bruma 7, Sanabria 6½, Geis 6½, Origi 7 | | Racing Genk | 2 | 5 Limbombe, 39 Plet | | Half-time: | 2-0 | | Referee: | Vassaras 5½ | | Attendance: | 24,761 | | Possession: | 55%-45% | | Total shots: | 13-15 | | MoM: | Kara |
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| | (4-3-3): Proto 7½, Ngcongca 7, Tshimanga 7½, Kara 8, Koulibaly 8, Nadson 6½, Buffel 7, Limbombe 7, Plet 6, Simaeys 6½, Vossen 6½ | | Baník Ostrava | 0 |
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| | (4-3-3): Nyland 7½, Fornasier 6½, Aké 7½, Oliver 6½, Naldo 7, Balanta 7, Promes 7, Martial 6, Córdoba 6½, Sanson 6, Baldé 6 | | Torino | 1 | 66 Isco | | Half-time: | 0-0 | | Referee: | Racalbuto 6 | | Attendance: | 27,982 | | Possession: | 55%-45% | | Total shots: | 20-8 | | MoM: | Reus |
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| | (4-3-3): Akinfeev 7, Abate 6½, De Sciglio 7½, Reus 8, Tah 7, Llorente 6½, Guerreiro 6, Isco 7, Krajnc 6, Mauro 7, Olaitan 7 | | FC Křbenhavn | 0 |
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| | (4-3-3): Weidenfeller 7, Sřrensen 8, Antunes 7½, Toutouh 6½, Kjćr 8, Freire 7, Bolańos 8, Eriksen 7, Dolberg 6, Cornelius 5½, Arshavin 6 | | Trabzonspor | 1 | 9 Halil | | Half-time: | 1-0 | | Referee: | Korac 6½ | | Attendance: | 24,003 | | Possession: | 48%-52% | | Total shots: | 6-16 | | MoM: | Olcan |
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| | (4-3-3): Onur Recep 7, Serkan 6½, Olcan 8, Sapara 7½, Celustka 6½, Mustafa 6½, Colman 6, Soner 7, Janko 6, Cardozo 6, Halil 6½ | | Liverpool | 1 | 77 Mané |
| | (4-3-3): Karius 6½, Clyne 7, Milner 6½, Can 8, Lovren 6½, Matip 6½, Wilson 6, Mané 7½, Sturridge 7½, Wijnaldum 7, Roberto Firmino 6 | | Villarreal | 1 | 56 Uche | | Half-time: | 0-1 | | Referee: | Braamhaar 6½ | | Attendance: | 22,823 | | Possession: | 55%-45% | | Total shots: | 17-12 | | MoM: | Moi Gómez |
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| | (4-3-3): Diego 7, Rukavina 7½, Jaume 7½, Bruno 6½ (56 Moi Gómez 8), Musacchio 7½, Chechu 6½, Aquino 7½, Pérez 6½, Uche 7, Trigueros 7, Jonathan 6 | | New York | 1 | 17 Parolo |
| | (4-3-3): Krul 7½, Kühne 6½, Johnson 7½, Nainggolan 7, Gabriel Paulista 6½, Wanyama 6, Giovani 7, Parolo 7, Altidore 6½, Cook 6½, Benayoun 6 |
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