| Round 5 | | Auxerre | 2 | 18 Isimat-Mirin, 31 Capoue | | Half-time: | 2-0 | | Referee: | Ziober 7½ | | Attendance: | 25,099 | | Possession: | 55%-45% | | Total shots: | 8-13 | | MoM: | Briand |
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| | (4-3-3): Aréola 7½, Yanga-Mbiwa 6½, Mavinga 7½, Özyakup 8, Isimat-Mirin 6 (57 Fanni 6½), Rekik 7½, Briand 8, John 7, Libertazzi 6, Capoue 7, Liviero 5½ | | Anderlecht | 1 | 52 Ilicevic |
| | (4-3-3): Proto 6½, Gillet 7½, Pocognoli 7, Dembélé 7½, Wuytens 7, Ramis 6½, Marecek 7, Ilicevic 7, Lukaku 7, Kerzhakov 6, Jonas 6½ | | Benfica | 2 | 42 Welliton, 67 César Peixoto | | Half-time: | 1-0 | | Referee: | Miu 7 | | Attendance: | 39,983 | | Possession: | 45%-55% | | Total shots: | 14-14 | | MoM: | Pereira |
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| | (4-3-3): Lopes 7, Pereira 8½, Eliseu 7½, Javi García 7, Maicon 6 (74 Bosingwa 6), Ricardo Carvalho 6, Ruben Amorim 6½, César Peixoto 6, Drogba 6½, Gourcuff 6, Welliton 6 | | Flamengo | 1 | 46 Belluschi | | 75 Everton | | (4-3-3): Bolat 7½, Leo Moura 8, Adriano 7, Everton 8, David 7, Samir 7, Belluschi 7, Marlos 6½, Lima 7½, Luiz Adriano 7, Wellington Nem 7 (47 Babel 7) | | Chelsea | 3 | 7 Pedro, 23 Khedira, 48 Koulibaly | | Half-time: | 2-1 | | Referee: | Craciun 8 | | Attendance: | 48,335 | | Possession: | 49%-51% | | Total shots: | 11-12 | | MoM: | Walker | | TV: | highlights |
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| | (4-3-3): Muslera 6½, Moses 7, Baines 6, Khedira 7, Koulibaly 7, Mustafi 6½, Callejón 7½, Pedro 5½ (56 Rüdiger 7), Pellé 6½, Fabregas 6½, Werner 6 | | Manchester City | 1 | 36 Soldado | | 76 Bravo | | (4-3-3): Bravo 6, Walker 8, Kolarov 6½, Touré 7½, Badstuber 7½, Stones 6½, Navas 7½, Sané 7, Soldado 7½, Bernardo Silva 6, Gabriel Jesus 7 | | Dynamo | 1 | 24og Fazio | | Half-time: | 1-1 | | Referee: | Gumienny 6 | | Attendance: | 43,515 | | Possession: | 43%-57% | | Total shots: | 6-7 | | MoM: | Çalhanoglu |
| | 48 Granero, 82 Blanco | | (4-3-3): Carrasso 6½, Mykhalyk 6½, Diakhaté 6, Harmash 7, Khacheridi 6½, Aloé 6½, Bystrov 6½, Blanco 6½, Milevskyi 7, Granero 6½, Kravets 6½ | | Roma | 1 | 3 Pazzini |
| | (4-3-3): Adler 7, Hysaj 7½, Young 6½, Çalhanoglu 7½, Fazio 7, Evans 6½, Schneiderlin 7, Kagawa 7, Pazzini 7, Tadic 6½, Kruse 7½ | | Fenerbahçe | 2 | 62 Sow, 67 Sow | | Half-time: | 0-0 | | Referee: | Ansuátegui Roca 6½ | | Attendance: | 30,675 | | Possession: | 42%-58% | | Total shots: | 10-15 | | MoM: | Dzeko |
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| | (4-3-3): Serkan 7½, Gökhan 7½, Cech 7½, Selçuk 7, Remzi Giray 6½, Egemen 6, Mehmet 7, Özer 6, Sow 7, Semih 5½, Burak 6½ | | Hansa Rostock | 1 | 66 Goretzka |
| | (4-3-3): Hitz 7, Piszczek 7½, Johnson 6½, Goretzka 8, Geromel 7, Rever 6½, Gündogan 6, Gentner 7 (65 Dejagah 7½), Dzeko 8, Benteke 7, Martins 6½ (62 Hasebe 6½) | | Feyenoord | 2 | 1 Van Wolfswinkel, 78 Vilhena | | Half-time: | 1-0 | | Referee: | Dinelli 6 | | Attendance: | 32,373 | | Possession: | 57%-43% | | Total shots: | 20-10 | | MoM: | Bruins | | TV: | highlights |
| | 84 Kongolo, 90+1 Vilhena | | (4-3-3): Alvarado 7½, Karsdorp 7½, Pieters 7½, Bruins 8, Kongolo 7½, Van Beek 6, Kuyt 7½, Vilhena 7, Van Wolfswinkel 7, De Guzman 6½, Schaken 7 | | Liverpool | 1 | 90+2 Valencic | | 51 Can | | (4-3-3): Pyatov 7, Vrsaljko 6½, Sakho 6½, Can 7½, Wimmer 7, Insúa 6½, Henderson 6, Valencic 6, Sřrum 6½, Badelj 6½, Origi 5½ | | Independiente | 3 | 3 Piatti, 36 Gutierrez, 63 Osvaldo | | Half-time: | 2-1 | | Referee: | Silinskas 6½ | | Attendance: | 31,633 | | Possession: | 51%-49% | | Total shots: | 11-8 | | MoM: | Carles Gil |
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| | (4-3-3): Orión 7, Matheu 6½, Galeano 7, Fernández 7, Otamendi 8, Vittor 5½, Fredes 6½, Piatti 7, Osvaldo 7, Tévez 6, Gutierrez 6 | | Deportivo | 1 | 43 Diamé | | 12 José Castro, 41 Riki, 54 Diamé | | (4-3-3): Guilherme 7½, Lekue 6½, Aarón Caricol 6½, Carles Gil 8½, Renato Silva 6½, José Castro 6½, Diamé 6, Guardado 7½, Adúriz 7, Riki 6, Sabin 7 (73 Arbilla 6) | | Internacional | 3 | 14 Felipe Anderson, 66 Giuliano, 89 Taison | | Half-time: | 1-0 | | Referee: | Norman 7½ | | Attendance: | 35,584 | | Possession: | 56%-44% | | Total shots: | 16-11 | | MoM: | Fernando |
| | 67 Giuliano | | (4-3-3): Alisson 7½, Danilo 7, Kléber 7½, Fernando 8, Hilton 8, André Bahia 6, Giuliano 8, Felipe Anderson 7½, Jô 6½, Fred 5½, Taison 6½ | | Săo Paulo | 0 |
| | 34 Robinho | | (4-3-3): Spiegel 6½, Maicon 7½, Wendell 6, Diego 7, Juan 7, Rodrigo Caio 6, Kelvin 6½, Renato Augusto 6, Willian 7½, Ganso 6½, Robinho 6 | | Manchester United | 2 | 37 Jones, 65 Matic | | Half-time: | 1-1 | | Referee: | Gusev 6½ | | Attendance: | 42,958 | | Possession: | 55%-45% | | Total shots: | 17-11 | | MoM: | Pogba | | TV: | highlights |
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| | (4-3-3): Kuszczak 6, Rafael 7½, Blind 7, Pogba 8, Jones 7½, McNair 6, Giovani 6, Lingard 6½ (66 Darmian 6½), Berbatov 7, Matic 7, Rooney 6 (66 Diouf 6) | | Brřndby | 2 | 16 Roberto Firmino, 47 Toivonen |
| | (4-3-3): Diego López 6½, Jantschke 6½, Lulic 7, Raúl García 7 (66 Gervinho 7), Zapata 6½, Ansaldi 5½, Selçuk 7, Mirallas 6½, Toivonen 6½, Adrián 6, Roberto Firmino 6 | | Newport County | 2 | 17 Rhodes, 56 Ayew | | Half-time: | 1-1 | | Referee: | Rosetti 6 | | Attendance: | 19,349 | | Possession: | 51%-49% | | Total shots: | 14-12 | | MoM: | Roncaglia |
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| | (4-3-3): Darlow 6½, Tomkins 7½, Bertrand 7, Badu 8, Clark 7½, Lascelles 6½, Cleverley 6½, Ayew 7, Rhodes 7, Livermore 6½, Phillips 6 | | Espanyol | 1 | 35 Roncaglia |
| | (4-3-3): Yoel 7½, Roncaglia 8, Víctor Álvarez 6½, Javi Márquez 7, Pareja 7½, Pinto 7, Verdú 6, Toribio 7, Tamudo 6, Ninkovic 7 (73 Leugers 6), Juanmi 6½ | | Spartak | 1 | 32 Rondón | | Half-time: | 1-1 | | Referee: | Vassaras 7½ | | Attendance: | 50,821 | | Possession: | 52%-48% | | Total shots: | 19-10 | | MoM: | Berezutsky | | TV: | live |
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| | (4-3-3): Ryzhikov 7, Mário Fernandes 6, Kombarov 7½, Torbinsky 7½, Berezutsky 8½, Kutepov 7, Zhirkov 6½, Dzagoev 8, Rondón 6½, Mamaev 7, Serderov 5½ | | Tottenham Hotspur | 1 | 4 Kane |
| | (4-3-3): Leno 7½, Cáceres 6, Vertonghen 7 (76 Flores 6), Locatelli 7, Dier 6, Ogbonna 7, Foor 6½, Nani 7, Kane 6 (74 Álvarez 6), Gabbiadini 5½, Wickham 5½ | | Round 3 | | Dynamo | 0 |
| | Half-time: | 0-1 | | Referee: | Van Vliet 6½ | | Attendance: | 41,243 | | Possession: | 48%-52% | | Total shots: | 11-18 | | MoM: | Kane |
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| | (4-3-3): Carrasso 5, Mykhalyk 6½, Diakhaté 6½, Harmash 7, Khacheridi 6½, Aloé 6½, Bystrov 6½, Blanco 6½, Milevskyi 7, Granero 7, Kravets 6½ | | Tottenham Hotspur | 3 | 45 Wickham, 73 Kane, 87 Kane |
| | (4-3-3): Leno 6, Cáceres 7, Vertonghen 7, Locatelli 7½, Dier 7, Ogbonna 7 (56 Álvarez 7), Foor 7, Nani 7, Kane 7½, Gabbiadini 6, Wickham 7 |
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