| Round 3 | | Ajax | 2 | 31 Lens, 36 Promes | | Half-time: | 2-0 | | Referee: | Hamar 8 | | Attendance: | 37,384 | | Possession: | 47%-53% | | Total shots: | 11-11 | | MoM: | Johnson | | TV: | live |
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| | (4-3-3): Zoet 7, Veltman 7, Viergever 6 (84 Ziyech 6), Klaassen 7, De Vrij 7, Ter Avest 6, Promes 6½, Lens 6, Huntelaar 7, Milik 6, Van Amersfoort 6½ | | Exeter City | 1 | 51 Austin |
| | (4-3-3): Foster 6½, Trippier 6½, Johnson 7½, Barry 7, Keane 6, Stephens 7 (58 Forrest 6), Walcott 6½, Redmond 7, Austin 7, Loftus-Cheek 7, Ibe 6 | | Baník Ostrava | 1 | 12 Totti | | Half-time: | 1-0 | | Referee: | Urrutia 8½ | | Attendance: | 17,326 | | Possession: | 53%-47% | | Total shots: | 13-15 | | MoM: | Perin |
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| | (4-3-3): Perin 7½, Hubocan 7½, Filipe Luis 6, Xhaka 7, Varane 7½, Medel 6, Traoré 6½, Meyer 7, Martínez 6½, Arnold 6, Totti 6½ | | Lazio | 0 |
| | 72 Defoe | | (4-3-3): Berisha 7½, Schelotto 7½, Radu 7, Onazi 7½, Maurício 6½ (61 Pasqual 7½), Bonera 6½, Ariaudo 7 (76 Antonelli 6), Verdi 6, Defoe 6½, Babacar 6, Mertens 6½ | | Barcelona | 2 | 9p Suárez, 15 Rakitic | | Half-time: | 2-1 | | Referee: | Knight 8 | | Attendance: | 61,522 | | Possession: | 51%-49% | | Total shots: | 18-13 | | MoM: | Clyne |
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| | (4-3-3): Ter Stegen 6, Abate 7, Maxwell 7½, Busquets 8, Bartra 6 (62 Dos Santos 7½), Mexès 5½, Feghouli 6½, Rakitic 7, Suárez 7, Gomez 6, Messi 6½ | | Ayr United | 1 | 6 Davis |
| | (4-3-3): Butland 7, Clyne 8½, Brunt 8, Fletcher 7, Shawcross 7, Cameron 6, Davis 7, Townsend 6½, Fletcher 7, McCarthy 6, Long 5½ | | Bayern München | 2 | 47 Lewandowski, 68 Müller | | Half-time: | 0-3 | | Referee: | Wieser 5½ | | Attendance: | 38,167 | | Possession: | 44%-56% | | Total shots: | 11-13 | | MoM: | Alaba |
| | 48 Müller | | (4-3-3): Andújar 6, Boateng 7, Alaba 8, Tolisso 7½, Djourou 6, Senderos 6, Coman 6½, Ribéry 7½, Lewandowski 7½, Pranjic 6, Müller 6½ | | Arsenal | 3 | 9 Nacho Monreal, 30 Özil, 44 Sánchez |
| | (4-3-3): Buffon 6, Bellerín 6, Nacho Monreal 7, Özil 7, Koscielny 7, Martins-Indi 6½ (72 Mertesacker 6), Koke 7, Sánchez 7½, Coquelin 6, Marchisio 6, Campbell 6 | | FC Porto | 4 | 2 Falcao, 45+1 Miranda, 52 João Moutinho, 73 André Silva | | Half-time: | 2-0 | | Referee: | Sedlacek 7 | | Attendance: | 43,520 | | Possession: | 56%-44% | | Total shots: | 18-12 | | MoM: | Miranda | | TV: | highlights |
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| | (4-3-3): Rui Patrício 7, Ricardo Esgaio 7, Alex Sandro 7, João Moutinho 8, Miranda 8½, Luisão 5 (79 Bruma 6), Marcelo 6, Philippe Coutinho 7, Falcao 7½, Otavio 7, André Silva 7 | | Paris SG | 0 |
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| | (4-3-3): Trapp 7, Marquinhos 6, Henrique 6, Verratti 6½, Sané 6½, Kimpembe 6, Traoré 7, Pastore 6½, Augustin 6, Jussiê 6, Neymar 6½ | | Lille | 3 | 62 Gaitán, 71 Lallana, 86 David Luiz | | Half-time: | 0-0 | | Referee: | Bazzoli 6½ | | Attendance: | 17,942 | | Possession: | 52%-48% | | Total shots: | 15-6 | | MoM: | David Luiz |
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| | (4-3-3): Lloris 7, Valencia 8, Sidibé 7½, Thauvin 8, David Luiz 8, Rodriguez 5½ (65 Jallet 6), Gaitán 7½, Lallana 7, Negredo 7, Flamini 6, Frey 7 | | CS Constantine | 0 |
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| | (4-3-3): Kameni 7½, El Kaddouri 7 (85 Taïder 6), Ghoulam 7½, Kouyaté 7½, Benatia 6½, Witsel 6, Belhanda 7, Brahimi 6, Slimani 7½, Bentaleb 6, N'Jie 6 | | Palermo | 2 | 6 Bernardeschi, 13 Bernardeschi | | Half-time: | 2-1 | | Referee: | Beschin 6½ | | Attendance: | 38,969 | | Possession: | 56%-44% | | Total shots: | 12-9 | | MoM: | Javi Manquillo | | TV: | live |
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| | (4-3-3): Sommer 6½, Zappacosta 7½, Romagnoli 7½, Jorginho 8, Criscito 6½, Astori 6, Candreva 8, Bernardeschi 7½, Destro 6½, Motta 6 (64 Éder 6), Vázquez 6 | | Valencia | 2 | 38 Hernández, 64 Hernández |
| | (4-3-3): Reina 6½, Javi Manquillo 8, Vargas 7, André Gomes 7, San Jose 6½, Reyes 6½, Santi Mina 6, Perotti 7, Hernández 6, Javi Fuego 7, Rodrigo 6 | | Round 4 | | Ayr United | 0 |
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| | (4-3-3): Butland 7, Clyne 7, Brunt 6, Fletcher 5½, Shawcross 6½, Cameron 6, Davis 7, Townsend 6½, Fletcher 6½, Long 7 (55 Robertson 5½), Berahino 6 | | FC Porto | 1 | 87 André Silva |
| | (4-3-3): Rui Patrício 7, Ricardo Esgaio 6½, Alex Sandro 7½, João Moutinho 8, Miranda 6½, Luisão 7, Marcelo 6½, Philippe Coutinho 8, Falcao 6½ (67 Guerreiro 7½), Otavio 6½, André Silva 5½ | | Exeter City | 1 | 50 Redmond | | Half-time: | 0-0 | | Referee: | Rrustemaj 6½ | | Attendance: | 19,677 | | Possession: | 44%-56% | | Total shots: | 5-12 | | MoM: | Lloris | | TV: | highlights |
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| | (4-3-3): Foster 8, Coleman 6½, Johnson 7½, Barry 7, Keane 6½, Stephens 6, Walcott 6½, Redmond 7, Austin 5½, Shelvey 7½, Dyer 5½ | | Lille | 0 |
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| | (4-3-3): Lloris 8, Valencia 6½, Sidibé 7, Thauvin 7, David Luiz 7½, Rodriguez 7½, Gaitán 7, Lallana 6½, Negredo 6½ (80 Tallo 6), Flamini 6, Frey 6 | | FC Basel | 1 | 64 Isco | | Half-time: | 0-2 | | Referee: | Meese 6½ | | Attendance: | 38,447 | | Possession: | 45%-55% | | Total shots: | 12-20 | | MoM: | Klaassen |
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| | (4-3-3): Weidenfeller 6, Dani Alves 6½, Jordi Alba 7½, Matuidi 7, Sarr 6½, Lichtsteiner 6½, Florenzi 7, Isco 7½, Enes 6½, Denis 7, Baldé 6 | | Ajax | 2 | 21 Lens, 29 Viergever |
| | (4-3-3): Zoet 7½, Veltman 7, Viergever 7, Klaassen 7½, De Vrij 6, Ter Avest 6, Promes 7, Lens 6½, Huntelaar 6½, Sneijder 7½, Van Amersfoort 6½ | | Helsingborg | 3 | 33 Eriksen, 53 Eriksen, 79 Agüero | | Half-time: | 1-0 | | Referee: | Strampe 6½ | | Attendance: | 40,728 | | Possession: | 57%-43% | | Total shots: | 19-9 | | MoM: | Sigurðsson |
| | 54 Diego Costa, 68 King | | (4-3-3): Schmeichel 6½, Azpilicueta 6½, Wendt 5½ (48 Durmisi 7), Sigurðsson 8, Christensen 7, Kjær 6, Zeneli 7½, Eriksen 7, Agüero 6, Diego Costa 6 (79 Wernbloom 6), King 6 | | Baník Ostrava | 2 | 56 Martínez, 76 Meyer |
| | (4-3-3): Perin 6, Hubocan 7 (76 Arnold 6), Filipe Luis 6½, Xhaka 6½, Varane 6½, Schär 6½, Traoré 6, Meyer 7, Martínez 6½, Kondogbia 6, Totti 6 | | Lazio | 1 | 12 Mertens | | Half-time: | 1-1 | | Referee: | Ziller 6½ | | Attendance: | 46,949 | | Possession: | 45%-55% | | Total shots: | 11-18 | | MoM: | Ramsey |
| | 47 Defoe, 79 Mertens | | (4-3-3): Berisha 7, Schelotto 6½, Radu 6½, Onazi 7, Maurício 7, Bonera 7, Ariaudo 6½, Verdi 6½, Defoe 6½, Babacar 6, Mertens 6 | | Accrington Stan. | 1 | 42 Shaw | | 30 Zaha, 76 Ramsey | | (4-3-3): Hart 7, Smalling 7, Shaw 6½, Alli 7½, Cahill 7, Williams 6½, Ward-Prowse 7½, Zaha 6, Sturridge 6½, Ramsey 8, Rashford 6½ | | Newcastle United | 1 | 75 Higuaín | | Half-time: | 0-0 | | Referee: | Kefalas 7½ | | Attendance: | 52,358 | | Possession: | 50%-50% | | Total shots: | 12-12 | | MoM: | Higuaín |
| | 53 Mbemba | | (4-3-3): Courtois 6, Zabaleta 7½, Götze 5½, Vidal 6½, Tah 6½, Mbemba 6, De Bruyne 6, Silva 6½, Higuaín 8, Wijnaldum 6½, Ayoze 5½ | | Borussia Dortmund | 1 | 54p Aubameyang | | 56 Podolski, 56 Höwedes, 70 Giménez, 77 Podolski, 88 Hazard | | (4-3-3): Akinfeev 7, Höwedes 7, Schmelzer 6 (76 Lavezzi 6), Bernard 7, Papastathopoulos 7, Giménez 7 (76 Schürrle 6), Ramires 7, Hazard 7, Aubameyang 7½, Podolski 5½, Fekir 6 | | Paris SG | 0 |
| | Half-time: | 0-3 | | Referee: | Colic 7½ | | Attendance: | 39,190 | | Possession: | 46%-54% | | Total shots: | 11-19 | | MoM: | Jorginho |
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| | (4-3-3): Trapp 5½, Marquinhos 7½, Henrique 6½, Verratti 6½, Sané 6½, Kimpembe 6½, Traoré 6, Pastore 7, Augustin 5½, Jussiê 5½, Neymar 7 | | Palermo | 3 | 7 Motta, 19 Bernardeschi, 21 Motta |
| | (4-3-3): Sommer 6, Zappacosta 7½, Criscito 7, Jorginho 8, Astori 7, Romagnoli 6½ (69 Bonaventura 6½), Candreva 7½, Bernardeschi 7, Destro 6, Motta 7, Vázquez 6 | | Real Madrid | 2 | 45 Bonucci, 90 Ibrahimovic | | Half-time: | 1-0 | | Referee: | Øvrebø 6 | | Attendance: | 66,326 | | Possession: | 54%-46% | | Total shots: | 23-10 | | MoM: | Kroos |
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| | (4-3-3): Navas 7½, Sergio Ramos 7½, Chiellini 7, Kroos 8½, Piqué 8, Bonucci 6½, Modric 6 (62 Pepe 7), Ronaldo 7½, Ibrahimovic 7, De Rossi 7, Bale 6 | | Nantes | 0 |
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| | (4-3-3): Ruffier 7, Colin 6½, Digne 6½, Gonalons 7, Mendy 6, Kurzawa 6, Sissoko 6½, Griezmann 6, Jean 6½ (72 Valbuena 6), Di María 5½, Benzia 5½ | | Valencia | 1 | 89p Hernández | | Half-time: | 0-1 | | Referee: | Alves Azevedo 6½ | | Attendance: | 41,110 | | Possession: | 48%-52% | | Total shots: | 16-17 | | MoM: | Linetty |
| | 90 Santi Mina | | (4-3-3): Reina 7, Javi Manquillo 7, Vargas 6½, André Gomes 7½, San Jose 6, Reyes 6, Santi Mina 6, Perotti 7, Hernández 6½, Javi Fuego 6½, Rodrigo 6½ | | Milan | 1 | 37 Quintero |
| | (4-3-3): Oblak 7½, Aurier 6½, Kolasinac 6½, Linetty 8, Javi Martínez 6½, Laporte 6, Volland 6, Mandzukic 6, Immobile 6½ (89 Musacchio 6), Quintero 5½, El Shaarawy 5½ |
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