Round 1 | Auxerre | 0 |
| Half-time: | 0-0 | Referee: | Boggi 6½ | Attendance: | 25,083 | Possession: | 55%-45% | Total shots: | 17-3 | MoM: | Aréola |
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| (4-3-3): Aréola 7½, Yanga-Mbiwa 7, Mavinga 6, Capoue 6½, Isimat-Mirin 7, Fanni 6½, Briand 7 (62 Doukouré 7½), John 7 (67 Verre 7½), Gameiro 6½, Danzé 7, Lacazette 5½ | Liverpool | 0 |
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| (4-3-3): Pyatov 7½, Vrsaljko 6½, Sakho 6½, Can 6, Wimmer 7, Insúa 6½, Henderson 6, Valencic 6½, Sřrum 5½, Badelj 6½, Origi 6½ | Benfica | 2 | 61 Drogba, 83 Trotta | Half-time: | 0-0 | Referee: | Rudy 5 | Attendance: | 44,699 | Possession: | 46%-54% | Total shots: | 10-14 | MoM: | Drogba | TV: | highlights |
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| (4-3-3): Lopes 7, Pereira 7½, Eliseu 5½, Javi García 6½, Maicon 7, Ricardo Carvalho 7, Ruben Amorim 7½, César Peixoto 6 (47 Cleiton Xavier 6½), Drogba 7½, Gourcuff 7 (55 Welliton 6½), Trotta 6½ | Anderlecht | 0 |
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| (4-3-3): Proto 7, Gillet 6½, Pocognoli 6½, Dembélé 7, Wuytens 6½ (51 Deschacht 6½), Ramis 6, Marecek 6, Ilicevic 6½, Lukaku 7 (53 Ebecilio 7½), Kerzhakov 5½, Jonas 7½ | Chelsea | 2 | 15 Pedro, 49p Llorente | Half-time: | 1-0 | Referee: | Tanner 6 | Attendance: | 47,919 | Possession: | 57%-43% | Total shots: | 16-11 | MoM: | Khedira |
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| (4-3-3): Muslera 6½, Moses 7, Baines 7½, Khedira 8, Koulibaly 7, Mustafi 6½, Callejón 7, Pedro 7, Llorente 7, Fabregas 7, Bellarabi 6½ | Hansa Rostock | 2 | 65 Dzeko, 71 Dzeko | 80 Gentner | (4-3-3): Hitz 6½, Piszczek 7, Johnson 7, Goretzka 7, Geromel 6½, Rever 7 (71 Polanski 6), Gentner 6, Schäfer 7, Dzeko 6½, Benteke 5½, Martins 5½ | Dynamo | 2 | 4 Kravets, 10 Harmash | Half-time: | 2-0 | Referee: | Dinelli 8 | Attendance: | 39,976 | Possession: | 60%-40% | Total shots: | 14-14 | MoM: | Nesmachnyi |
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| (4-3-3): Carrasso 7, Diakhaté 7, Nesmachnyi 7½, Harmash 6½, Khacheridi 7, Aloé 7, Bystrov 7½, Blanco 7, Milevskyi 7, Granero 7½, Kravets 7 | Espanyol | 0 |
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| (4-3-3): Yoel 7½, Roncaglia 6, Víctor Álvarez 6, Javi Márquez 7, Pareja 5½, Pinto 7, Verdú 6½, Toribio 6, Tamudo 6, Ninkovic 7 (73 Leugers 6), Juanmi 6½ | Fenerbahçe | 0 |
| Half-time: | 0-1 | Referee: | Walton 7½ | Attendance: | 36,601 | Possession: | 55%-45% | Total shots: | 16-8 | MoM: | Řdegaard |
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| (4-3-3): Serkan 6½, Gökhan 7½, Bekir 7½, Řdegaard 8, Remzi Giray 7½, Serdar 5½, Mehmet 7½, Cech 7 (65 Selçuk 7), Sow 7, Semih 6, Burak 6 | Deportivo | 1 | 9p Riki | 24 Bruno Gama | (4-3-3): Guilherme 7, Lekue 7½, Jaume 8, Carles Gil 7, José Castro 6½, Colotto 6, Diamé 7½, Guardado 6½, Riki 6½, Bruno Gama 6, Sabin 6 | Feyenoord | 1 | 21 Vilhena | Half-time: | 1-2 | Referee: | Onufer 6½ | Attendance: | 39,961 | Possession: | 53%-47% | Total shots: | 15-12 | MoM: | De Guzman | TV: | highlights |
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| (4-3-3): Vermeer 5½, Hutchinson 8, Pieters 7, De Guzman 8½, Kongolo 7, Maduro 6½, Schaken 6½ (60 Dingsdag 8), Vilhena 7, Van Wolfswinkel 6, Castaignos 6, Kazim-Richards 7 (82 Schenkeveld 6) | Roma | 3 | 6 Tadic, 13 Kagawa, 59 Young |
| (4-3-3): Adler 5, Hysaj 6½, Young 7, Çalhanoglu 6½, Fazio 6½, Evans 7, Tadic 6½, Kagawa 6½, Pazzini 6½, Pizarro 6½ (59 Noboa 6), Kruse 6 | Independiente | 0 |
| Half-time: | 0-1 | Referee: | Knight 6 | Attendance: | 42,992 | Possession: | 42%-58% | Total shots: | 13-13 | MoM: | Walker | TV: | highlights |
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| (4-3-3): Orión 6, Matheu 6, Vittor 6½, Fernández 7½, Otamendi 6½, Galeano 6, Fredes 7½, Mancuello 6½, Osvaldo 6½, Busse 6, Tévez 6½ | Manchester City | 2 | 40 Sterling, 74 Bernardo Silva |
| (4-3-3): Bravo 6½, Walker 7½, Kolarov 7, Touré 7, Badstuber 7 (74 Rodríguez 7), Stones 6, Navas 7½, Sterling 7, Soldado 7, Bernardo Silva 6½, Gabriel Jesus 6½ | Internacional | 2 | 42 Jô, 48 Marcelo | Half-time: | 1-3 | Referee: | Halsey 6½ | Attendance: | 47,445 | Possession: | 55%-45% | Total shots: | 15-10 | MoM: | Kléber |
| 41 Fernando, 43 Danilo, 45 Marcelo, 67 Felipe Anderson, 80 Hilton | (4-3-3): Alisson 5½, Danilo 7, Kléber 7½, Fernando 6½, Marcelo 7, Hilton 6½, Joăo Pedro 7, Felipe Anderson 7, Jô 7½, Fred 6, Taison 7½ | Brřndby | 4 | 12p Toivonen, 22 Toivonen, 45+1 Roberto Firmino, 55 Toivonen |
| (4-3-3): Diego López 6, Jantschke 6½, Lulic 6½, Raúl García 7, Corluka 6, Zapata 7½, Selçuk 7, Mirallas 6, Toivonen 6½, Adrián 5, Roberto Firmino 6½ | Manchester United | 0 |
| Half-time: | 0-1 | Referee: | López Nieto 5½ | Attendance: | 47,654 | Possession: | 54%-46% | Total shots: | 4-12 | MoM: | Pogba | TV: | live |
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| (4-3-3): Kuszczak 6½, Rafael 7 (84 Januzaj 6), Blind 7, Pogba 8, Jones 7, McNair 6½, Giovani 8, Lingard 8, Berbatov 7, Matic 6½, Rooney 5½ | Tottenham Hotspur | 1 | 6 Kane | 1 Cáceres, 37 Nani, 50 Foor | (4-3-3): Leno 7, Cáceres 6½, Vertonghen 7½, Locatelli 6½, Dier 7, Ogbonna 6, Foor 6½, Nani 6½, Kane 6½, Gabbiadini 5½, Wickham 5½ | Newport County | 2 | 9 Cleverley, 18og Samir | Half-time: | 2-1 | Referee: | Young 7 | Attendance: | 19,315 | Possession: | 57%-43% | Total shots: | 11-11 | MoM: | Ayew |
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| (4-3-3): Darlow 6½, Tomkins 7, Bertrand 7½, Badu 6, Clark 7, Lascelles 6½, Cleverley 7, Ayew 7½, Rhodes 6½, Livermore 7, Phillips 6½ | Flamengo | 2 | 31 Marlos, 58 Vágner Love |
| (4-3-3): Muriel 6½, Luiz Antônio 6, Adriano 6 (73 Babel 7), Everton 6½, Samir 6½, David 6, Belluschi 6½, Marlos 7, Vágner Love 6½, Luiz Adriano 5½, Emerson 6 | Spartak | 5 | 19 Zhirkov, 33 Kombarov, 49 Rondón, 55 Torbinsky, 62 Rondón | Half-time: | 2-0 | Referee: | Londono 8 | Attendance: | 39,206 | Possession: | 46%-54% | Total shots: | 13-10 | MoM: | Kombarov |
| 72 Khodyrev | (4-3-3): Ryzhikov 6, Mário Fernandes 6, Kombarov 7½, Torbinsky 7½, Berezutsky 7, Kutepov 7, Zhirkov 6, Dzagoev 4½ (60 Khodyrev 7), Rondón 7, Mamaev 7, Serderov 6 | Săo Paulo | 1 | 87 Willian |
| (4-3-3): Spiegel 7, Maicon 6, Juan 6, Ganso 7, Rodrigo Caio 6½, Roger Carvalho 7, Kelvin 6½, Renato Augusto 6½, Willian 6, Diego 6, Robinho 6½ (74 Victor Andrade 6½) | Round 2 | Anderlecht | 2 | 24 Dembélé, 44 Lukaku | Half-time: | 2-0 | Referee: | Franceschini 6 | Attendance: | 27,994 | Possession: | 55%-45% | Total shots: | 13-13 | MoM: | Rondón |
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| (4-3-3): Proto 7½, Gillet 6½ (77 Ebecilio 6), Pocognoli 7, Dembélé 7, Wuytens 7½, Ramis 6 (55 Chyhrynskyi 7), Marecek 6, Ilicevic 7, Lukaku 7, Kerzhakov 6, Jonas 7 | Spartak | 0 |
| 17 Dzagoev, 41 Kutepov, 67 Torbinsky | (4-3-3): Ryzhikov 7, Mário Fernandes 6½, Kombarov 7, Torbinsky 6½, Berezutsky 7½, Kutepov 6, Zhirkov 6, Dzagoev 7 (82 Khodyrev 6), Rondón 7½, Mamaev 6½, Serderov 5½ | Brřndby | 1 | 22p Toivonen | Half-time: | 1-1 | Referee: | Bolognino 6 | Attendance: | 28,821 | Possession: | 47%-53% | Total shots: | 9-11 | MoM: | Toivonen |
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| (4-3-3): Diego López 6½, Jantschke 6, Lulic 7, Raúl García 7, Corluka 7½, Zapata 6½, Selçuk 6, Mirallas 6½, Toivonen 7½, Adrián 6, Roberto Firmino 6 | Auxerre | 3 | 10 Gameiro, 46 Gameiro, 75 Capoue | 52 Fanni | (4-3-3): Aréola 6½, Yanga-Mbiwa 7, Mavinga 7, Capoue 7, Isimat-Mirin 6½, Fanni 6½, Briand 7, John 6½, Gameiro 7½, Danzé 6½, Lacazette 6½ | Deportivo | 2 | 9 Guardado, 70 Adúriz | Half-time: | 1-0 | Referee: | Cinciripini 7 | Attendance: | 34,554 | Possession: | 51%-49% | Total shots: | 12-14 | MoM: | Badu |
| 15 Sabin, 36 Carles Gil, 78 Renato Silva, 90+1 Bruno Gama | (4-3-3): Guilherme 6½, Lekue 7½, Jaume 8, Carles Gil 6 (83 Aarón Caricol 6), Renato Silva 6½, Colotto 7, Diamé 7½, Guardado 7, Adúriz 6½, Sabin 6, Bruno Gama 6 | Newport County | 1 | 78p Rhodes |
| (4-3-3): Darlow 6½, Tomkins 7, Bertrand 6½, Badu 8½, Clark 7½, Lascelles 7, Cleverley 7, Ayew 6, Rhodes 7, Livermore 6½, Phillips 6 | Espanyol | 2 | 27 Tamudo, 38 Pareja | Half-time: | 2-1 | Referee: | Řvrebř 7½ | Attendance: | 33,402 | Possession: | 56%-44% | Total shots: | 17-9 | MoM: | Otamendi |
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| (4-3-3): Yoel 6½, Roncaglia 6½, Víctor Álvarez 6½, Javi Márquez 7, Pareja 7½, Pinto 7, Verdú 6½, Toribio 7, Tamudo 7, Ninkovic 6, Juanmi 7 | Independiente | 1 | 9 Mancuello |
| (4-3-3): Orión 6½, Matheu 7, Vittor 6, Fernández 7, Otamendi 7½, Galeano 6, Fredes 7, Mancuello 7, Osvaldo 6½, Busse 7, Tévez 6 | Flamengo | 1 | 62 Emerson | Half-time: | 0-0 | Referee: | Braamhaar 5½ | Attendance: | 39,624 | Possession: | 43%-57% | Total shots: | 3-15 | MoM: | Adriano |
| 17 Marlos, 53 David | (4-3-3): Muriel 7, Luiz Antônio 6, Adriano 7½, Everton 7, Samir 6, David 6½, Belluschi 7, Marlos 6½, Vágner Love 6½, Luiz Adriano 6, Emerson 6½ | Internacional | 0 |
| 77 Marcelo | (4-3-3): Alisson 7½, Danilo 7, Kléber 6½, Fernando 6½ (53 Mariano 7½), Marcelo 7, Hilton 6, Giuliano 6½, Felipe Anderson 7, Jô 7, Joăo Pedro 7, Taison 6½ | Hansa Rostock | 1 | 89 Polanski | Half-time: | 0-1 | Referee: | Meese 6 | Attendance: | 28,883 | Possession: | 48%-52% | Total shots: | 11-10 | MoM: | Piszczek |
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| (4-3-3): Hitz 6½, Piszczek 8, Johnson 7½, Goretzka 7, Rever 7, Geromel 6, Hasebe 7, Schäfer 6, Dzeko 6½ (65 Polanski 7), Benteke 6½, Martins 6½ | Manchester United | 2 | 40 Giovani, 57 Berbatov |
| (4-3-3): Kuszczak 6, Rafael 7, Blind 7½, Pogba 7½, Jones 7, McNair 5½, Giovani 7½, Lingard 7, Berbatov 6½, Matic 6½, Rooney 6 | Liverpool | 1 | 18p Sřrum | Half-time: | 1-1 | Referee: | Arena 6½ | Attendance: | 30,730 | Possession: | 51%-49% | Total shots: | 12-9 | MoM: | Llorente |
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| (4-3-3): Pyatov 6½, Vrsaljko 7, Sakho 7½, Can 7, Wimmer 7½, Insúa 7, Henderson 7, Valencic 5½, Sřrum 6, Badelj 6½, Origi 6½ | Chelsea | 1 | 1 Fabregas |
| (4-3-3): Muslera 6½, Moses 8, Baines 7, Khedira 6½, Koulibaly 6½, Mustafi 6, Callejón 6, Pedro 6½, Llorente 8, Fabregas 6, Bellarabi 6 | Manchester City | 3 | 2 Sané, 21 Sané, 36 Sané | Half-time: | 3-1 | Referee: | Alves Azevedo 8 | Attendance: | 47,422 | Possession: | 54%-46% | Total shots: | 13-8 | MoM: | Touré |
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| (4-3-3): Bravo 7½, Walker 6½, Kolarov 7½, Touré 8, Badstuber 5½ (74 Rodríguez 6), Stones 6½, Navas 6, Sané 7½, Soldado 7½, Bernardo Silva 6½, Gabriel Jesus 6½ | Dynamo | 1 | 22 Milevskyi | 38 Khacheridi | (4-3-3): Carrasso 6½, Diakhaté 6½, Nesmachnyi 6½, Harmash 7, Khacheridi 7, Mykhalyk 6½, Bystrov 7½, Blanco 7, Milevskyi 7, Granero 6½, Kravets 6 | Roma | 2 | 31 Fazio, 55 Young | Half-time: | 1-0 | Referee: | Cesari 7½ | Attendance: | 50,242 | Possession: | 55%-45% | Total shots: | 18-12 | MoM: | Young |
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| (4-3-3): Adler 6, Hysaj 7½, Young 7½, Çalhanoglu 7½, Fazio 7, Evans 7, Tadic 7, Kagawa 7½, Pazzini 7, Pizarro 6 (59 Noboa 7), Kruse 6½ | Benfica | 1 | 90 Eliseu |
| (4-3-3): Lopes 6½, Pereira 6½, Eliseu 6½, Javi García 6½, Maicon 6, Ricardo Carvalho 6, Ruben Amorim 5½, César Peixoto 6, Drogba 6½, Gourcuff 6, Welliton 6½ | Săo Paulo | 2 | 71 Ganso, 88 Wendell | Half-time: | 0-1 | Referee: | Pyanikh 6½ | Attendance: | 37,649 | Possession: | 46%-54% | Total shots: | 17-11 | MoM: | Karsdorp |
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| (4-3-3): Spiegel 6½, Maicon 6, Wendell 7, Diego 6½, Juan 6½, Rodrigo Caio 6, Kelvin 7, Renato Augusto 6½, Willian 6½, Ganso 6½, Robinho 6 | Feyenoord | 2 | 8 Van Wolfswinkel, 90 Pieters |
| (4-3-3): Alvarado 7, Karsdorp 8, Pieters 6½, Hutchinson 7½, Kongolo 7, Van Beek 6, Schaken 7, Vilhena 7, Van Wolfswinkel 7½, De Guzman 6, Biseswar 6½ | Tottenham Hotspur | 3 | 11 Kane, 48 Kane, 72p Kane | Half-time: | 1-1 | Referee: | Racalbuto 5½ | Attendance: | 36,045 | Possession: | 57%-43% | Total shots: | 13-5 | MoM: | Foor |
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| (4-3-3): Leno 6, Cáceres 8½, Vertonghen 6½, Locatelli 7½, Dier 7, Ogbonna 5½ (56 Álvarez 7½), Foor 8½, Nani 7, Kane 7½, Gabbiadini 6, Wickham 6½ | Fenerbahçe | 2 | 15og Locatelli, 66 Sow |
| (4-3-3): Serkan 7, Gökhan 6½, Bekir 7½, Řdegaard 6½, Remzi Giray 6½, Serkan 6, Mehmet 7, Cech 5½, Sow 7, Semih 5½, Burak 5½ |
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