| Round 5 | | Arsenal | 1 | 26p Biereth | | Half-time: | 1-1 | | Referee: | Strampe 6½ | | Attendance: | 38,300 | | Possession: | 52%-48% | | Total shots: | 13-11 | | MoM: | Coulibaly | | TV: | highlights |
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| | (4-3-3): Johnstone 7, Williams 7, Coulibaly 8, Mkhitaryan 7½, Azpilicueta 7, Pablo 6½, Fábio Vieira 7, Grealish 7, Biereth 7½, Xhaka 7½, Balogun 6½ | | Villarreal | 1 | 31 Jackson |
| | (4-3-3): Jörgensen 7½, Traoré 6, Moreno 6½, Manu Morlanes 7½, Lenglet 7, Eder Militão 6½ (51 Danjuma 6½), Daramy 6½, Yéremy Pino 6, Jackson 7, Joan Jordán 6½, Azmoun 5½ | | Aston Villa | 2 | 21 Kolo-Muani, 28 Abraham | | Half-time: | 2-0 | | Referee: | Korac 7 | | Attendance: | 40,342 | | Possession: | 49%-51% | | Total shots: | 23-8 | | MoM: | Eggestein |
| | 27 Kjær, 47 Ramsey | | (4-3-3): Pope 7½, McKennie 7, Viña 7, Højbjerg 7½, Mings 7, Keane 6, Kjær 6½, João Félix 6½, Abraham 7, Ramsey 6½, Kolo-Muani 6 | | B.Mönchengladbach | 0 |
| | 19 Reitz, 52 Itakura, 77 Hofmann | | (4-3-3): Sippel 7½, Scally 6, Martha 7, Eggestein 7½, Itakura 6½, Savona 6, Hofmann 6½, Ndoye 7, Raúl 7, Reitz 6, Moukoko 6½ (51 Klaassen 7) | | Atalanta | 3 | 12 Evjen, 35 Szymanski, 65 Frattesi | | Half-time: | 2-0 | | Referee: | Svanbäck 9 | | Attendance: | 24,569 | | Possession: | 55%-45% | | Total shots: | 22-8 | | MoM: | Bellanova |
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| | (4-3-3): Scuffet 7½, Bellanova 8, Bensebaini 7½, De Roon 8, Martínez Quarta 7, Carboni 7, Evjen 6½, Minamino 7½, Piccoli 5½ (51 Frattesi 7), Szymanski 7½, Tiago Tomás 6 | | Valencia | 0 |
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| | (4-3-3): Soria 7½, Foulquier 7 (46 Thierry Correia 7½), Samuel Lino 6½, Parejo 5½, Gabriel Paulista 6½, Diakhaby 6, Marvin 6, Hélder Costa 6, Rubén Sobrino 5½, Kondogbia 6½, Rodrigo 5½ | | Chelsea | 0 |
| | Half-time: | 0-1 | | Referee: | Alves Azevedo 6 | | Attendance: | 40,312 | | Possession: | 44%-56% | | Total shots: | 13-14 | | MoM: | Gil |
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| | (4-3-3): Meslier 7½, Chalobah 7½, Junior Firpo 6½, William Carvalho 6½ (62 Gil 8), Humphreys 6½, Ricardo Esgaio 6, Horta 7½, João Pedro 6, Jiménez 6½, Weghorst 6, Pléa 7 (52 James 8) | | FC Porto | 1 | 42 Pepê |
| | (4-3-3): Remiro 7½, Manafá 7, Sanusi 7 (80 David Carmo 6), Stephen Eustáquio 7, Danilo 7½, Otávio 6, Nanu 7½, Pepê 7, Willian 6½ (75 Kostoulas 6½), Uribe 7, Galeno 6½ | | FC Twente | 2 | 10 Wilson, 36 Lokonga | | Half-time: | 2-2 | | Referee: | Pinto Correia 5 | | Attendance: | 13,171 | | Possession: | 50%-50% | | Total shots: | 16-15 | | MoM: | Stengs | | TV: | highlights |
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| | (4-3-3): Drommel 6½, Meunier 7½, Blind 7, Berghuis 7, Van Hecke 7½, St Juste 6, Stengs 8, Lokonga 6, Wilson 7½, Bruns 6½, George 6 | | Sevilla | 2 | 8 En-Nesyri, 26 Fran García | | 2 En-Nesyri | | (4-3-3): Dmitrovic 7, Álex Sola 7, Fran García 6½, Jota 7½, Gudelj 6, Gnagnon 6, Álex Pozo 7, Álex Moreno 7, En-Nesyri 6½, Willian 7, El Haddadi 6½ | | Lille | 3 | 14 Bayo, 32 Bayo, 39 Bamba | | Half-time: | 3-1 | | Referee: | Constantin 7½ | | Attendance: | 18,070 | | Possession: | 46%-54% | | Total shots: | 11-14 | | MoM: | Karazor |
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| | (4-3-3): Chevalier 5½, Weah 6½, Reinildo 7, André 7, Tiago Djaló 7½, José Fonte 6½, Zhegrova 6½, Bamba 7½, Bayo 5½ (85 Cabella 6), Gomes 6, Kamano 6 | | VfB Stuttgart | 2 | 13 Führich, 82 Ito |
| | (4-3-3): Flekken 6½, Maffeo 7, Ito 7, Karazor 8, Kempf 7½, Ullrich 6½, Endo 6, Führich 7½, Perea 6, Mangala 6½, Zuber 6½ | | Napoli | 1 | 51 Politano | | Half-time: | 0-0 | | Referee: | Martincik 8 | | Attendance: | 49,565 | | Possession: | 57%-43% | | Total shots: | 14-11 | | MoM: | Davis |
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| | (4-3-3): Pau López 7, Zanoli 6½, Friedl 7, Oriol Romeu 7½, Llorente 7½, Maksimovic 6½, Gonçalo Guedes 7, Politano 7½, Fekir 6, Zerbin 6, Retegui 6 | | Dundee United | 0 |
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| | (4-3-3): Barkas 7, Dodô 6, Mykolenko 7, Baumgartner 6½, Uduokhai 6½, Davis 8, McCausland 6½, Adeyemi 6½, Alario 7 (51 Berardi 7½), Barrenechea 6, Sarr 7 (63 Holding 6) | | RB Leipzig | 2 | 1 Willock, 74 Soumaré | | Half-time: | 1-1 | | Referee: | McCluskey 7½ | | Attendance: | 36,111 | | Possession: | 55%-45% | | Total shots: | 13-9 | | MoM: | Adarabioyo | | TV: | highlights |
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| | (4-3-3): Blaswich 6, O'Brien 7, Ritchie 7, Haidara 7, Adarabioyo 7½, Ampadu 7, Murphy 7, Soumaré 7½, Sørloth 6 (55 Javi Manquillo 6), Willock 7, Nketiah 5½ | | Tottenham Hotspur | 1 | 29 Sargent | | 38 Harrison | | (4-3-3): Forster 6½, Pedro Porro 7 (72 Bowden 7), Colwill 7, Lo Celso 6½, Mandi 7, Coady 6½, Tolisso 7, Golovin 7, Sargent 6½, Harit 6, Harrison 6 | | Sassuolo | 2 | 41 Samu Castillejo, 59 Raspadori | | Half-time: | 1-0 | | Referee: | Young 7 | | Attendance: | 20,390 | | Possession: | 53%-47% | | Total shots: | 12-13 | | MoM: | Rrahmani |
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| | (4-3-3): De Gea 8, Pedersen 6½, Kolasinac 6½, Bajrami 7, Rrahmani 8, Viti 6½, Boloca 7, Samu Castillejo 7½, Dovbyk 7½, Lopez 6, Raspadori 7 | | Spartak | 0 |
| | 53 Bailly | | (4-3-3): Aréola 7, Reynolds 6½, Manu Sánchez 6, Pasalic 7, Bednarek 7, Bailly 6½, Moses 6, Haraldsson 6, Embolo 6½, Nico 6, Lee 5½ | | Sporting | 2 | 10 Mitoma, 31 Beto | | Half-time: | 2-1 | | Referee: | Brito Arceo 8 | | Attendance: | 48,527 | | Possession: | 55%-45% | | Total shots: | 13-9 | | MoM: | Mitoma |
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| | (4-3-3): Rui Silva 7, Geny Catamo 6½, José Marsà 7½, Daniel Bragança 6 (77 Balogh 7½), Tomás Araújo 7, Coates 6½, Rafa 7, Mitoma 7½, Beto 7, Anderson Talisca 6½, Toni 6½ | | Manchester City | 1 | 3 Mané |
| | (4-3-3): Schmeichel 7, Wan-Bissaka 6½, Burn 6½, Bruno Fernandes 7, Orban 6, Maguire 6, Mount 6½, Mané 7, Essende 7, Longstaff 5½, Scarlett 5½ | | Torino | 2 | 12 Eze, 20 Mikel Merino | | Half-time: | 2-0 | | Referee: | Detruche 6½ | | Attendance: | 68,446 | | Possession: | 55%-45% | | Total shots: | 14-7 | | MoM: | Nübel | | TV: | live |
| | 8 Zabarnyi | | (4-3-3): Nübel 8, Gatti 6½, Cambiaso 7½, Rabiot 7, Zabarnyi 7½, Vivian 6½, Greenwood 7½, Eze 7, Mikel Merino 7, Jones 6, Schade 5½ | | Fiorentina | 0 |
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| | (4-3-3): Skorupski 7½, Kayode 6, Theate 7, Mandragora 7, Schouten 6½, Ranieri 6½, Zanotti 6½, Rots 6½, Solanke 6½, Svanberg 6½, Nzola 6 | | Round 3 | | Atalanta | 1 | 7og Bruno Fernandes | | Half-time: | 1-2 | | Referee: | Sarvan 6 | | Attendance: | 24,550 | | Possession: | 49%-51% | | Total shots: | 13-11 | | MoM: | Burn |
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| | (4-3-3): Scuffet 6½, Bellanova 8, Bensebaini 6½ (46 Kouamé 7½), De Roon 7½, Martínez Quarta 7½, Carboni 6½, Evjen 6½, Minamino 7½, Piccoli 6½, Szymanski 7, Tiago Tomás 6½ (68 Frattesi 6) | | Manchester City | 2 | 34 Mané, 45+2 Essende |
| | (4-3-3): Schmeichel 6½, Wan-Bissaka 6½, Burn 8½, Bruno Fernandes 6½, Orban 6½, Maguire 6½, Mount 6, Mané 7½, Essende 7½, Bennacer 6, Scarlett 6 | | Lille | 2 | 28 Bamba, 49 Bayo | | Half-time: | 1-0 | | Referee: | Walton 6 | | Attendance: | 18,084 | | Possession: | 45%-55% | | Total shots: | 7-11 | | MoM: | Zhegrova |
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| | (4-3-3): Chevalier 7, Weah 7½, Reinildo 7, André 7, Tiago Djaló 6½, José Fonte 6½, Zhegrova 8, Bamba 7, Bayo 6½, Gomes 6 (64 Gudmundsson 6½), Kamano 6 | | B.Mönchengladbach | 0 |
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| | (4-3-3): Sippel 7½, Scally 7½, Martha 7, Eggestein 7 (54 Klaassen 6½), Itakura 7, Savona 6½, Hofmann 7, Ndoye 6½, Raúl 7½, Koné 7, Moukoko 6½ |
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