| Round 5 | | Ajax | 1 | 39 Locatelli | | Half-time: | 1-1 | | Referee: | Bennett 7 | | Attendance: | 63,201 | | Possession: | 59%-41% | | Total shots: | 17-8 | | MoM: | Aďt-Nouri | | TV: | live |
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| | (4-3-3): Leno 7, Rensch 6, Aďt-Nouri 8, Locatelli 8, Pau Torres 6½, Mćhle 6½, Arda 6, Doku 7, Lewandowski 7, Pellegrini 6½, Havertz 7 | | Real Madrid | 1 | 21 Richarlison |
| | (4-3-3): Rulli 7, Mazraoui 7 (51 Montiel 7), Chilwell 6½, Fabián 6½, Can 6, García 6½, Engels 6½, Di María 6½, Richarlison 7, Modric 7 (78 Youssef Chermiti 5½), Williams 6 | | Bayer Leverkusen | 2 | 23 Hincapié, 90 Hudson-Odoi | | Half-time: | 1-1 | | Referee: | Knight 7 | | Attendance: | 22,465 | | Possession: | 51%-49% | | Total shots: | 10-11 | | MoM: | Hincapié | | TV: | highlights |
| | 85 Dragovic | | (4-3-3): Hrádecký 7, Retsos 7½, Hincapié 8, Andrich 7½, Dragovic 6½, Fosu-Mensah 6 (49 Valentin 7), Adli 7, Hudson-Odoi 8, Schick 7, Füllkrug 6½, Kanga 5½ | | Bayern München | 1 | 26 Gallagher |
| | (4-3-3): Casteels 7, Henrichs 6½, Günter 6½, Gallagher 8, Acerbi 7 (82 Lavia 6), Kalulu 6, Cuadrado 6½, Gnabry 7, Morata 6½, Sudakov 7½, Archer 6 | | Boca Juniors | 2 | 5 Díaz, 16 Martínez | | Half-time: | 2-0 | | Referee: | Dean 7 | | Attendance: | 59,993 | | Possession: | 57%-43% | | Total shots: | 19-12 | | MoM: | Raphinha |
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| | (4-2-3-1): Martínez 7½, Molina 7, Olivera 6½, Mac Allister 7½, Araújo 7, Pacho 7, Valverde 6½, Raphinha 8, Martínez 7½, Lookman 7, Díaz 7 | | Deportivo | 0 |
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| | (4-3-3): Szczesny 7½, Baku 7, Digne 6, Bentancur 6, Mosquera 7, Stanisic 6, Kesler-Hayden 6½, Mikel 6½, Delap 6½ (51 Agoumé 6½), Barnes 6½, Torres 6 | | Flamengo | 1 | 28 Pedro | | Half-time: | 1-1 | | Referee: | Grabher 6 | | Attendance: | 42,191 | | Possession: | 48%-52% | | Total shots: | 11-6 | | MoM: | Maldini |
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| | (4-3-3): Matheus 6½, Matheuzinho 6½, Marusic 7½, Joăo Gomes 7½, Bremer 7, Lucas 6½, Thiago Maia 7, Talles Magno 7, Pedro 7, Pulgar 6½, Yuri Alberto 6½ | | Milan | 1 | 27 Kökçü |
| | (4-3-3): Audero 7, Sardella 7, Carrasco 7, Kökçü 7½, Koulibaly 6½, Yoro 5½, Tsyhankov 6½, Maldini 7½, Gómez 6½, Nianzou 5½, Kean 6 | | Inter | 0 |
| | Half-time: | 0-1 | | Referee: | Sedlacek 6½ | | Attendance: | 48,543 | | Possession: | 45%-55% | | Total shots: | 9-15 | | MoM: | Nuno Mendes |
| | 45+1 Soucek | | (4-3-3): Kepa 6½, Veltman 6½, Milner 6½, Bissouma 6½, Ajer 7, Vestergaard 6, Soucek 6½, Damsgaard 7, Pinamonti 7, Mendy 6½, Iheanacho 6 | | Sporting Braga | 1 | 41 Rodrygo |
| | (4-3-3): Diogo Costa 7½, Dumfries 7, Nuno Mendes 8, Bruno Guimarăes 7½, Dimarco 7½, Romero 7, Saka 6½, Szoboszlai 7, Joăo Neves 6½, Barella 7, Rodrygo 6½ | | Liverpool | 3 | 4 Lozano, 5 Zielinski, 88 Guerreiro | | Half-time: | 2-0 | | Referee: | Ancion 6½ | | Attendance: | 40,911 | | Possession: | 58%-42% | | Total shots: | 24-5 | | MoM: | Bassey |
| | 35 Dzeko | | (4-3-3): Trapp 7, Ginter 7, Guerreiro 7, Çalhanoglu 7½, De Vrij 7½, Giménez 5½ (75 Kessié 7), Correa 6½, Lozano 7, Dzeko 7, Zielinski 6½, Suárez 6½ | | Independiente | 0 |
| | 33 Paredes, 60 Franco, 72 Meza, 82 Simeone | | (4-3-3): Armani 7½, Mercado 6½, Bassey 7½, Aleix 6½, Pezzella 6½, Franco 6, Buendia 6½, Meza 6, Simeone 7, Paredes 6, Maza 6½ | | Lyon | 0 |
| | Half-time: | 0-0 | | Referee: | Bolognino 7½ | | Attendance: | 78,073 | | Possession: | 45%-55% | | Total shots: | 16-11 | | MoM: | Marquinhos | | TV: | live |
| | 83 Osimhen | | (4-3-3): Alisson 7½, Koundé 7 (60 Reus 7), Robertson 6½, Bernardo Silva 7, Marquinhos 7½, Van Dijk 6½, Salah 7½, Vinícius Júnior 7½, Vlahovic 6½, Osimhen 5½, Griezmann 6½ (75 El Aynaoui 6) | | Marseille | 0 |
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| | (3-4-1-2): Courtois 7½, Hakimi 7½, Akanji 6½, Fofana 7, Konaté 6, Pavard 6½, Dembélé 7, Tielemans 6½, Lukaku 7½, Olise 6, Thuram 6½ | | Manchester United | 1 | 50 Walker | | Half-time: | 0-0 | | Referee: | Brignoccoli 8 | | Attendance: | 48,582 | | Possession: | 44%-56% | | Total shots: | 8-15 | | MoM: | Hernández | | TV: | highlights |
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| | (4-3-3): Mendy 7, Walker 6½, Romagnoli 7½, Koke 7½, Diomandé 6, Tanganga 6½ (85 Alex Telles 6), Calabria 5½, Ruggeri 6, Insigne 7, Freuler 6, Dybala 5½ | | Barcelona | 0 |
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| | (4-2-3-1): Sommer 8, Di Lorenzo 7½, Hernández 8, Rodri 6½, Saliba 7½, Stones 7 (56 Timber 6), Yamal 7½, Rice 6½, Watkins 7, Bellingham 7, Wirtz 7 | | Newcastle United | 1 | 18p Marmoush | | Half-time: | 1-1 | | Referee: | Cardona 7 | | Attendance: | 59,944 | | Possession: | 64%-36% | | Total shots: | 8-5 | | MoM: | Joelinton |
| | 32 Marmoush, 56 Gravenberch, 62 Gravenberch | | (3-5-2): Verbruggen 6½, Van De Ven 7, Guehi 6½, Tah 7½, Goretzka 8, Joelinton 8, Frimpong 8, Raum 7½, Musiala 6½, Gravenberch 6½, Marmoush 7 | | FC Schalke 04 | 1 | 45 Arrey-Mbi |
| | (4-3-3): Neuer 6½, Kehrer 6, Gosens 7½, Amiri 7, Arrey-Mbi 7, Mittelstädt 6, Wolf 7, Draxler 7½, Woltemade 6½, Samardzic 5½, Waldschmidt 5½ | | Paris SG | 1 | 65 Trossard | | Half-time: | 0-0 | | Referee: | Franceschini 8 | | Attendance: | 35,852 | | Possession: | 42%-58% | | Total shots: | 18-16 | | MoM: | Palhinha |
| | 41 Marc Cucurella, 45 Zubimendi, 46 Neymar | | (4-3-3): Josep 6½, Semedo 6, Marc Cucurella 6½, Zubimendi 6½, Mancini 6, Badiashile 6, Almiron 6½, Trossard 7, De Ketelaere 7, Cristante 6½ (68 Kamara 6), Neymar 6 | | Feyenoord | 1 | 88 Lamptey | | 43 Brozovic | | (4-3-3): Ter Stegen 6½, Lamptey 7, Mendy 6½, Palhinha 8, Laporte 7, Fabinho 6, Brozovic 7, Malen 7 (77 Van Den Berg 7), Benzema 7, Amrabat 6½, Depay 6 | | Strasbourg | 0 |
| | Half-time: | 0-1 | | Referee: | Řvrebř 8 | | Attendance: | 27,413 | | Possession: | 50%-50% | | Total shots: | 6-22 | | MoM: | Caci | | TV: | highlights |
| | 9 Bellegarde, 45+2 Ajorque | | (4-3-3): Sels 6, Sakai 6½, Caci 8, Gueye 7½, Djiku 7½, Doukouré 7, Diarra 6½, Thomasson 7½, Ajorque 6½, Bellegarde 6½, Niang 6 | | Borussia Dortmund | 2 | 7 Haaland, 75 Mbappé |
| | (3-4-3): Oblak 7, Bastoni 8, Upamecano 6½, Kimmich 6½, Rúben Dias 7, De Bruyne 7, Alexander-Arnold 7, Haaland 6½, Kane 6½, Mbappé 6½, Kvaratskhelia 7 | | Round 3 | | Manchester United | 1 | 83 Ilaix | | Half-time: | 0-2 | | Referee: | Sandra 6 | | Attendance: | 47,991 | | Possession: | 44%-56% | | Total shots: | 11-19 | | MoM: | Koke |
| | 73 Freuler | | (4-3-3): Mendy 4½, Walker 7, Romagnoli 7½, Koke 8, Diomandé 6, Tanganga 6½, Van De Beek 6, Ruggeri 6, Insigne 6½ (71 Ilaix 6½), Freuler 7 (74 Sottil 6), Dybala 6½ | | Marseille | 4 | 6 Thuram, 11 Lukaku, 68p Lukaku, 72 Thuram |
| | (3-4-1-2): Courtois 5½, Hakimi 7½, Akanji 7½, Fofana 7½, Konaté 6½, Pavard 7, Dembélé 7, Tielemans 7, Lukaku 6½, Olise 6, Thuram 6 | | Flamengo | 1 | 59 Talles Magno | |
| | (4-3-3): Matheus 6, Matheuzinho 5½, Marusic 6½, Joăo Gomes 7, Bremer 7, Lucas 6½, Thiago Maia 6½, Talles Magno 6, Pedro 6½, Pulgar 6, Yuri Alberto 5½ | | Borussia Dortmund | 3 | 29 Kane, 45 Alexander-Arnold, 69 Kane |
| | (3-4-3): Oblak 6, Bastoni 7, Upamecano 6½, Kimmich 7½, Rúben Dias 7, De Bruyne 7, Alexander-Arnold 8, Haaland 6½, Kane 7, Mbappé 6½, Kvaratskhelia 7 |
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