| Round 3 | | Feyenoord | 2 | 20 Musah, 74 Mendy | | Half-time: | 1-0 | | Referee: | Allison 9½ | | Attendance: | 47,306 | | Possession: | 59%-41% | | Total shots: | 17-13 | | MoM: | Mendy | | TV: | highlights |
| | 14 Palhinha, 59 Reyna | | (4-3-3): Ter Stegen 7½, Trippier 6 (47 Mukiele 7½), Mendy 8½, Kroos 7½, Laporte 7 (49 Reyna 7½), Geertruida 6½, Musah 7½, Malen 7½, Benzema 7, Palhinha 6½, Depay 7 | | Strasbourg | 0 |
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| | (4-3-3): Sels 7, Lala 6½, Caci 7, Veretout 7½, Perrin 6½, Doukouré 6, Gueye 5½, Liénard 6, Ajorque 6, Bellegarde 6½, Niang 6 | | Napoli | 1 | 15 De Vrij | | Half-time: | 1-0 | | Referee: | Knight 6½ | | Attendance: | 47,543 | | Possession: | 51%-49% | | Total shots: | 15-10 | | MoM: | Zanoli |
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| | (4-3-3): Benítez 6½, Zanoli 8½, Wendell 7½, Oriol Romeu 7½, De Vrij 7, Botman 6½ (78 Friedl 6), Callejón 6, Politano 7½, Vitinha 7, Fekir 6½, Pedrinho 6½ | | Aston Villa | 2 | 52 João Félix, 77 Coman | | 68 Kjær | | (4-3-3): Pope 6½, Konsa 7, Mæhle 7½, Højbjerg 6½, Tomori 7, Mings 6½, Kjær 6, Coman 6½, Fábio Silva 7, Doku 6½ (78 Nmecha 6), João Félix 6½ | | West Ham United | 1 | 78 Antonio | | Half-time: | 0-1 | | Referee: | Rennie 7½ | | Attendance: | 44,226 | | Possession: | 42%-58% | | Total shots: | 14-19 | | MoM: | Alaba | | TV: | live |
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| | (4-3-3): Bravo 5½, Diogo Dalot 5½, Emerson Palmieri 6½, Pablo Fornals 7, Aguerd 5½, Dawson 6½ (74 King 6), Bowen 7, Benrahma 6, Antonio 6½, Cornet 5½, Ings 6 | | Borussia Dortmund | 2 | 8 Haaland, 62 Kane |
| | (3-4-3): Donnarumma 7½, Kimmich 8½, Alaba 8½, De Bruyne 8, Rúben Dias 7, Foden 7½, Alexander-Arnold 7½, Haaland 8, Kane 7½, Mbappé 7½, Davies 6½ | | Round 4 | | Ajax | 4 | 27 Lewandowski, 45+1 Pau Torres, 74 Carrasco, 85p Lewandowski | | Half-time: | 2-1 | | Referee: | Dean 7 | | Attendance: | 46,833 | | Possession: | 50%-50% | | Total shots: | 18-14 | | MoM: | Pellegrini | | TV: | highlights |
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| | (4-3-3): Rui Patrício 7, Dumfries 7, Carrasco 7, Pellegrini 8, Pau Torres 7½, Varane 7, Havertz 7, Elmas 5½, Lewandowski 7½, Belotti 6½, Hazard 5½ | | Napoli | 1 | 34 Politano |
| | (4-3-3): Benítez 7, Zanoli 7, Wendell 7, Oriol Romeu 7, De Vrij 6, Botman 6, Callejón 5½, Politano 7, Fekir 7, Vitinha 5½, Pedrinho 6 | | Aston Villa | 2 | 68 João Félix, 89 João Félix | | Half-time: | 0-0 | | Referee: | Wieser 6 | | Attendance: | 49,640 | | Possession: | 51%-49% | | Total shots: | 16-18 | | MoM: | Handanovic |
| | 75 Coman | | (4-3-3): Pope 7, Konsa 7, Mæhle 7, Højbjerg 7½, Tomori 7, Mings 6½, Kjær 6½, Coman 7, Fábio Silva 6½, Neuhaus 6½, João Félix 6½ | | Real Madrid | 0 |
| | 86 Can, 87 Tah | | (4-3-3): Handanovic 8, Danilo 7½, Chilwell 8, Modric 7 (51 Can 7), Tah 7½, Christensen 5½, Brahim 7, Di María 7, Lacazette 6, Ødegaard 6½, Isak 5½ | | Barcelona | 3 | 4 Watkins, 51 Nico Williams, 57 Watkins | | Half-time: | 1-1 | | Referee: | Ancion 6½ | | Attendance: | 73,115 | | Possession: | 55%-45% | | Total shots: | 16-6 | | MoM: | Rodri |
| | 85 Wirtz | | (4-5-1): Simón 7, Di Lorenzo 7, Hernández 6½, Rodri 7½, Saliba 7, Stones 6, Nico Williams 5½ (71 Gavi 6), Bellingham 7, Watkins 7, Pedri 6½, Wirtz 7 | | Liverpool | 1 | 12 Jota |
| | (4-3-3): Trapp 6½, Koundé 7 (46 Ginter 7½), Guerreiro 6½, Çalhanoglu 7, Marquinhos 6, Bastoni 6½, Locatelli 6½, Jota 6½, Giroud 6½, Luis Alberto 6, Dzeko 5½ | | Bayer Leverkusen | 0 |
| | Half-time: | 0-0 | | Referee: | Bazzoli 5½ | | Attendance: | 22,447 | | Possession: | 40%-60% | | Total shots: | 6-16 | | MoM: | Rüdiger |
| | 4 Bellarabi, 24 Kadlec, 39 Kadlec, 70 Andrich, 83 Hincapié, 89 Füllkrug | | (4-3-3): Hrádecký 6, Gumny 6, Hincapié 7, Andrich 7, Dragovic 7 (67 Iago 6½), Kadlec 5½, Aránguiz 7, Adli 6, Füllkrug 6½, Hudson-Odoi 6, Bellarabi 5½ | | Lyon | 3 | 50 Vinícius Júnior, 71og Iago, 85 Carvajal | | 7 Salah, 27 Griezmann, 68 Bernardo Silva | | (4-4-2): Alisson 6, Carvajal 7, João Cancelo 7, Gündogan 7, Rüdiger 7½, Van Dijk 7, Bernardo Silva 7, Vinícius Júnior 7½, Osimhen 7½, Griezmann 7, Salah 6½ | | Chelsea | 1 | 25 Weghorst | | Half-time: | 1-1 | | Referee: | Rajh 6 | | Attendance: | 46,071 | | Possession: | 45%-55% | | Total shots: | 7-10 | | MoM: | Chiesa |
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| | (4-3-3): Meslier 6, Ricardo Esgaio 6½ (67 Nelson 6), Vertonghen 7½, Götze 7, Chalobah 6, Hateboer 6, Horta 6½, João Pedro 6½, Weghorst 6½, William Carvalho 7, Pléa 6½ | | Sporting Braga | 2 | 17og Horta, 72 Rafael Leão |
| | (3-4-1-2): Diogo Costa 6½, Romero 7, Dimarco 7, Szoboszlai 7½, Le Normand 7, Bruno Guimarães 7, Chiesa 8, Barella 7, Gonçalo Ramos 6½, Saka 7, Rafael Leão 7 | | FC Porto | 2 | 46 Uribe, 48 Uribe | |
| | (4-3-3): Remiro 5½, Manafá 6, Sanusi 7½, Pepe 6½, Danilo 7, Mbemba 7, Nanu 7, Galeno 7, Pepê 7, Uribe 6, Adrián 5½ | | West Ham United | 3 | 26 Emerson Palmieri, 52 Pablo Fornals, 60 Diogo Dalot |
| | (4-3-3): Bravo 6, Diogo Dalot 7, Emerson Palmieri 8½, Benrahma 7½, Aguerd 7 (74 Zappacosta 6), Dawson 6½, Bowen 8, Pablo Fornals 8, Antonio 6½, Downes 6, Ings 6 | | Flamengo | 2 | 10 Pedro, 45+2 Marusic | | Half-time: | 2-0 | | Referee: | Dinelli 6½ | | Attendance: | 43,666 | | Possession: | 44%-56% | | Total shots: | 10-10 | | MoM: | Thiago | | TV: | live |
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| | (4-3-3): Matheus 7, Matheuzinho 6 (55 Lucas 6), Marusic 7½, João Gomes 6½, Bremer 6½, David Luiz 6, Thiago Maia 6, Talles Magno 7, Pedro 7, Gerson 6, Yuri Alberto 6 | | FC Schalke 04 | 0 |
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| | (4-3-3): Neuer 7, Kehrer 7½, Mittelstädt 7, Thiago 7½, Hummels 7, Klostermann 6, Volland 7, Draxler 7½, Woltemade 7½, Ziyech 7, Waldschmidt 6 | | Manchester City | 1 | 34og Franco | | Half-time: | 1-1 | | Referee: | Trentalange 5½ | | Attendance: | 49,068 | | Possession: | 58%-42% | | Total shots: | 15-6 | | MoM: | Longstaff | | TV: | highlights |
| | 2 Mount, 41 Sterling, 80 Mount | | (4-3-3): Schmeichel 6½, Wan-Bissaka 6, Robertson 8, Longstaff 8½, Maguire 7, Guehi 6, Kulusevski 7, Mané 7½, Scarlett 6½, Mount 7, Sterling 6½ | | Independiente | 1 | 40 Cervi | | 21 Simeone, 55 Cervi, 70 Buendia | | (4-1-3-2): Armani 7, Mercado 7, Kannemann 7, Paredes 7½, Pezzella 7, Franco 6, Buendia 6, Cervi 6, Simeone 6½, Aleix 6½, Simón 6½ | | Marseille | 3 | 35 Thuram, 79 Thuram, 90 Bennacer | | Half-time: | 1-2 | | Referee: | Meese 8 | | Attendance: | 57,218 | | Possession: | 51%-49% | | Total shots: | 15-17 | | MoM: | Hakimi |
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| | (4-3-3): Courtois 7, Pavard 7, Hakimi 8, Fofana 7½, Disasi 6½, Konaté 7, Dembélé 7½, Witsel 7, Kolo-Muani 7, Bennacer 7, Thuram 7½ | | Bayern München | 2 | 31 Lukaku, 32 Koopmeiners |
| | (4-3-3): Casteels 6, Henrichs 6½, Günter 6½, Gallagher 7, Sildillia 5½, Bornauw 6½, Cuadrado 7, Gnabry 6½, Lukaku 6½ (90 Laimer 6), Koopmeiners 6, Morata 5½ | | Strasbourg | 0 |
| | Half-time: | 0-0 | | Referee: | Piraux 7½ | | Attendance: | 27,387 | | Possession: | 51%-49% | | Total shots: | 14-12 | | MoM: | Veretout |
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| | (4-3-3): Sels 7, Lala 6½, Caci 6½, Veretout 8, Perrin 7, Doukouré 6½, Gueye 7 (78 Djiku 6), Liénard 6½, Ajorque 7, Bellegarde 6, Niang 7 | | Boca Juniors | 1 | 87 Martínez |
| | (4-2-2-2): Onana 7½, Molina 6½, Acuña 7, Martínez 7, Araújo 6½, Mac Allister 6, Valverde 7, De Paul 7 (61 Vanderson 7½), Álvarez 7½, Martínez 7, Núñez 7 |
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