| Round 3 | | 1.FC Union Berlin | 1 | 61 Mittelstädt | | Half-time: | 0-0 | | Referee: | Waddel 6 | | Attendance: | 41,419 | | Possession: | 51%-49% | | Total shots: | 12-7 | | MoM: | Gordon |
| | 24 Mćhle, 41 Buongiorno | | (4-2-3-1): Rřnnow 8, Mćhle 8, Mittelstädt 7, Buongiorno 6½, Doekhi 8, Kemlein 7, Kühn 7, Til 7, Woltemade 7½, Tiago Tomás 8, Gil 7½ | | Hearts | 0 |
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| | (4-3-3): Gordon 8½, Spittal 6, Kingsley 6½, Devlin 6½, Kent 6, Findlay 6, Kabangu 5½, Cláudio Braga 6½, Wilson 6½, Kyziridis 6, Shankland 5½ | | Gręmio | 1 | 10 Carballo | | Half-time: | 1-0 | | Referee: | Hill 7 | | Attendance: | 45,525 | | Possession: | 47%-53% | | Total shots: | 11-11 | | MoM: | Villasanti |
| | 59 Ferreira | | (4-3-3): Éverson 7½, Fagner 6½, Carlos Augusto 7, Villasanti 8, Otávio 6½, Wooh 6½, Bitello 6, Zé Rafael 7, Hladkyi 6½, Carballo 6½ (69 Nathan 7), Ferreira 6½ | | Mallorca | 0 |
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| | (4-3-3): Johansson 6½, Corchia 7½, Cabrera 7, Ruiz De Galarreta 7½, Valjent 7, Raillo 7 (51 Dresevic 7), André Gomes 7, Tello 7½, Prats 7, Alfon 5½, Kadewere 6 | | Lokomotiv | 3 | 13 Golovin, 25 Smolov, 50 Smolov | | Half-time: | 2-1 | | Referee: | Dowd 5½ | | Attendance: | 29,916 | | Possession: | 51%-49% | | Total shots: | 16-8 | | MoM: | Kruglov |
| | 68 Miranchuk, 78 Barinov, 90 Bijol | | (4-3-3): Khudyakov 6½, Gocholeishvili 7½, Kruglov 7½, Batrakov 6½, Bijol 7, Diveev 5½ (56 Miranchuk 6), Miranchuk 7, Golovin 6½, Smolov 6½, Barinov 7, Isidor 6 | | Leeds United | 2 | 45 Harrison, 90+1p Rutter |
| | (4-3-3): Jörgensen 6, Kristensen 7, Struijk 7, Aaronson 7, Koch 7 (61 Forshaw 7), Wöber 6½, Yunus 6, Harrison 6, Rutter 6½, Antonio 6½, Bamford 5½ | | Parma | 2 | 4 Bonny, 33 Vlasic | | Half-time: | 2-0 | | Referee: | Bennett 6½ | | Attendance: | 27,811 | | Possession: | 56%-44% | | Total shots: | 12-11 | | MoM: | Darmian |
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| | (4-3-3): Dragowski 7, O'Brien 6½, Darmian 8½, Bernabé 7½, Solet 6½, Circati 6 (56 Paloschi 6), Fini 7, Vlasic 7½, Bonny 7 (80 Masiello 6), Esposito 6½, Benedyczak 6 | | FC Porto | 1 | 79 Otavio | | 9 Taremi | | (4-3-3): Bishesari 7, Corona 7½, Alex Telles 6, Uribe 7½, Stephen Eustáquio 7½, Cédric 6½, Carrillo 6½, Otavio 7, Aboubakar 6½, Buonanotte 7, Taremi 6½ | | Rayo Vallecano | 2 | 1 Isi Palazón, 54 Isi Palazón | | Half-time: | 1-0 | | Referee: | Foy 6½ | | Attendance: | 14,594 | | Possession: | 43%-57% | | Total shots: | 17-10 | | MoM: | Oblyakov | | TV: | live |
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| | (3-4-3): Plizzari 6½, Mumin 6½, Lejeune 7, Isi Palazón 7, Ciss 6½, Óscar Valentín 7, Catena 6½, Santi Comesańa 7, Álvaro 7½, Unai López 6½, Nteka 7 | | CSKA | 1 | 59 Oblyakov | | 14 Makeev, 74 Silyanov | | (4-3-3): Safonov 7, Silyanov 7, Álvaro Carreras 7, Oblyakov 8, Morozov 7, Makeev 6½, Chernikov 6½, Ejuke 7, Necid 7, Sucic 7, Zhemaletdinov 6 | | Round 4 | | 1.FC Köln | 1 | 3 Rexhbecaj | | Half-time: | 1-2 | | Referee: | Reed 6½ | | Attendance: | 39,961 | | Possession: | 48%-52% | | Total shots: | 11-12 | | MoM: | Jung |
| | 79 Hübers | | (4-3-3): Jaros 5½, Wolf 6, Jakobs 6, Skhiri 7½, Soldo 7, Hübers 6, Schindler 6, Khadra 5½, Lemperle 6, Rexhbecaj 7, Tigges 5½ | | Hertha BSC Berlin | 2 | 32 Kudus, 41 Kudus |
| | (4-4-2): Sánchez 6, Maffeo 7 (86 Akpoguma 6), Jung 8½, Aitor Paredes 7, Hincapié 7, Pablo 7, Jauregizar 7½, Samuel Lino 6½ (86 Dilrosun 6), Gabriel Jesus 7, Kudus 7, Johnson 6½ | | Atalanta | 1 | 58 Scamacca | | Half-time: | 0-1 | | Referee: | D'Urso 6½ | | Attendance: | 21,126 | | Possession: | 42%-58% | | Total shots: | 12-10 | | MoM: | Battaglia |
| | 19 Maldini, 48 Bonfanti, 85 Krstovic | | (4-3-3): Dibusz 6½, Calabresi 7, Bernasconi 6½, Luciano 6½, Okoli 6½, Bonfanti 6, Keďta 7 (69 Cassa 7), Maldini 6, Scamacca 7, Abu Fani 6½ (61 Zachariassen 7), Krstovic 6½ | | Udinese | 1 | 28 Asensio |
| | (4-3-3): Skorupski 7, Isla 8, Masina 7, Fofana 6½, Battaglia 8, Opoku 6, Ehizibue 7½, Asensio 6½ (47 Beruatto 6½), Beto 7, Pereyra 6, Shomuradov 7½ | | Fort. Düsseldorf | 0 |
| | Half-time: | 0-2 | | Referee: | Styles 7 | | Attendance: | 43,039 | | Possession: | 37%-63% | | Total shots: | 6-21 | | MoM: | Calafiori |
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| | (4-3-3): Ortega 5½, Zimmermann 6½, Gavory 6, Amiri 6½, Itakura 6½, Hilgers 6, Pléa 6½, Klaus 5½, Vermeij 6½, Demirbay 7 (63 André 5½), Undav 5½ | | Real Betis | 3 | 24 Mbeumo, 29 Lucas Beraldo, 67 Díaz |
| | (4-3-3): Milinkovic-Savic 6, Laimer 7½, Calafiori 8½, Varela 8, Gatti 7½, Lucas Beraldo 8, Semenyo 8, Díaz 7½, Dovbyk 7, O'Reilly 6, Mbeumo 7½ | | Hearts | 2 | 38 Cláudio Braga, 63 Devlin | | Half-time: | 1-3 | | Referee: | Dean 6 | | Attendance: | 17,635 | | Possession: | 41%-59% | | Total shots: | 10-19 | | MoM: | Holm |
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| | (4-3-3): Gordon 6, Spittal 6, Kingsley 7, Devlin 7, Kent 6½, Findlay 6, Kabangu 5½, Cláudio Braga 6½, Wilson 6½, Kyziridis 6, Shankland 6 | | RB Leipzig | 3 | 16 Sarr, 23 Zuber, 40 Nilsson |
| | (4-3-3): Omlin 6, Holm 8, Kahl 7, Seiwald 8, Helander 6½, Tihi 7½, Almqvist 7 (55 Larsson 8), Zuber 8, Nilsson 7, Banzuzi 6½, Sarr 7 (56 Ajeti 7) | | Leeds United | 2 | 26 Rutter, 70 Rutter | | Half-time: | 1-0 | | Referee: | Grabher 7½ | | Attendance: | 34,292 | | Possession: | 49%-51% | | Total shots: | 18-9 | | MoM: | Jörgensen | | TV: | highlights |
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| | (4-3-3): Jörgensen 7½, Kristensen 6½, Struijk 7½, Aaronson 7, Koch 7, Wöber 6½, Yunus 7, Harrison 7, Rutter 7, Antonio 6 (70 Ayling 6), Bamford 7 (79 Forshaw 7) | | Gręmio | 0 |
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| | (4-3-3): Éverson 7½, Joăo Pedro 6½, Carlos Augusto 7½, Villasanti 7½, Otávio 7, Wooh 7, Bitello 6, Zé Rafael 7, Hladkyi 7, Carballo 6, Ferreira 6½ | | Mallorca | 2 | 45+1 Tello, 81 Tello | | | 68 Raillo, 75 Kadewere | | (4-3-3): Johansson 6½, Corchia 6½, Cabrera 7, Ruiz De Galarreta 7, Valjent 7, Raillo 6½, André Gomes 7, Tello 6½, Prats 6½, Brasanac 6, Kadewere 7 | | Rayo Vallecano | 2 | 53 Ciss, 59 Isi Palazón |
| | (3-4-3): Plizzari 7, Mumin 7½, Lejeune 7, Isi Palazón 7, Ciss 7½, Óscar Valentín 8, Catena 6½, Santi Comesańa 6½, Álvaro 7, Unai López 6, Nteka 6 | | Tottenham Hotspur | 3 | 16 Spence, 28 Latte Lath, 57 Latte Lath | | Half-time: | 2-1 | | Referee: | López Nieto 6½ | | Attendance: | 26,467 | | Possession: | 56%-44% | | Total shots: | 18-7 | | MoM: | Aránguiz |
| | 46 Latte Lath | | (4-3-3): Dieng 6½, Wan-Bissaka 5½ (83 Black 6), Spence 6½ (84 Williams-Barnett 6), McNair 7½, Danso 7½, Brittain 6½, Antony 7½, Mejbri 7½, Latte Lath 7, Pellistri 5½, Rogers 7½ | | Hansa Rostock | 2 | 21 Kübler, 50 Eggestein |
| | (4-3-3): Padilla 7, Kübler 7, Chilwell 7½, Karazor 6½, Kempf 6½, Sagnan 6, Aránguiz 8, Arnautovic 7, Biereth 7, Kampl 7½, Eggestein 6 | | Vélez Sársfield | 0 |
| | Half-time: | 0-1 | | Referee: | Arena 5½ | | Attendance: | 36,263 | | Possession: | 44%-56% | | Total shots: | 4-14 | | MoM: | Giannetti |
| | 25 Orellano | | (4-3-3): Rulli 6½, Guidara 6½, Ortega 6½, Ramírez 6½, Giannetti 8, De Los Santos 6, Cristaldo 7½, Orellano 6½, Calleri 7, Castro 5½, Carranza 7 | | FC Schalke 04 | 2 | 9 Kubo, 53 Kubo | | 30 Minamino | | (4-3-3): Suzuki 6½, Morita 7½, Truffert 6, Minamino 6½ (79 Sano 6), Tuta 8, Friedl 6, Hatate 7, Kubo 7, Nketiah 6 (84 Jeong 6), Kamara 6½, Lee 6½ | | Zaragoza | 2 | 5 Luis Alberto, 55 Enis | | Half-time: | 1-1 | | Referee: | Cardona 7½ | | Attendance: | 39,422 | | Possession: | 43%-57% | | Total shots: | 16-12 | | MoM: | Brown |
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| | (4-3-3): Turati 6½, Assignon 7, Brown 8, Isco 7, Ahmetcan 6½, Aidoo 7, Larrazabal 6½, Williams 6, Milik 7, Luis Alberto 6½, Enis 5½ | | Parma | 1 | 10 Esposito |
| | (4-3-3): Dragowski 6½, O'Brien 7, Darmian 7, Bernabé 6½ (56 Masiello 7), Solet 7½, Circati 6½, Fini 7, Vlasic 6½, Bonny 7, Esposito 6, Benedyczak 5½ |
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