| Round 4 | | Aston Villa | 2 | 9 Werner, 83 Bailey | | Half-time: | 1-1 | | Referee: | Onufer 5½ | | Attendance: | 41,192 | | Possession: | 49%-51% | | Total shots: | 12-9 | | MoM: | Shaw |
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| | (4-3-3): Samba 6½, Krafth 7½, Maatsen 7½, Bentancur 7½, Orban 6½, Mings 7, Buendia 6 (65 Pedro Gonçalves 7), Bailey 6½, Füllkrug 6½, Rodrigo Muniz 6, Werner 7½ | | Shakhtar | 1 | 25 Álvarez | | 35 Lepenant, 63 Martial | | (4-3-3): Lopes 7½, Calabria 7, Shaw 8, Casemiro 7½, Tiago Djaló 7, Touré 6, Eriksen 7, Martial 6, Álvarez 7½, Lepenant 7½, Fofana 6 | | Barcelona | 1 | 56 Natan | | Half-time: | 0-0 | | Referee: | Wiley 6½ | | Attendance: | 48,677 | | Possession: | 54%-46% | | Total shots: | 15-8 | | MoM: | Elustondo | | TV: | highlights |
| | 78 Abel Ruiz | | (4-3-3): Neto 7, Elustondo 8½, Mingueza 8, Vidal 7, Natan 7½, Chumi 6, Traoré 8, Malcom 7½, Abel Ruiz 6½, Paco Alcácer 6, Kaio 6½ | | Bayern München | 0 |
| | 66 Arrey-Mbi | | (4-3-3): Flekken 7, Geny Catamo 6, Kolasinac 6½, Lucas Torreira 8, Vităo 6½, Stanisic 6, Beste 6, Iwobi 6½, Marc Roca 6, Mukhtar 7 (56 Arrey-Mbi 6), Hack 5½ | | FC Utrecht | 2 | 2 De Jong, 48 Kerk | | Half-time: | 1-1 | | Referee: | Blankenstein 7½ | | Attendance: | 23,607 | | Possession: | 51%-49% | | Total shots: | 14-10 | | MoM: | Gyökeres | | TV: | highlights |
| | 3 De Jong, 20 Bakker | | (4-3-3): Noppert 6, Troupée 6½, Bakker 6, Amrabat 6½, St Juste 7, Hall 6, Berghuis 6½, Kerk 6½, De Jong 6½, Haller 6, Dessers 7 | | Kaiserslautern | 2 | 5 Marmoush, 80 Aktürkoglu |
| | (3-4-3): Trapp 6, Vanderson 6, Führich 7, N'Dicka 6½, Rüdiger 6½, Alaba 5½, Marmoush 7, Tielemans 7½, Gyökeres 7½, Çalhanoglu 7, Aktürkoglu 6 | | Fiorentina | 2 | 59 Dolberg, 69 Zakaria | | Half-time: | 0-0 | | Referee: | Larsen 5½ | | Attendance: | 44,437 | | Possession: | 57%-43% | | Total shots: | 19-6 | | MoM: | Rodríguez |
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| | (4-3-3): Perin 6½, Dodô 7, Marusic 6½, Rodríguez 8, Magnani 7½, Vogliacco 6 (56 Maleh 6½), Lucas Moura 6, Ikoné 6½, Dolberg 7, Zakaria 7, Toni 7½ | | Ajax | 0 |
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| | (4-3-3): Bizot 7, Veltman 7, Denswil 6½, Götze 6½ (63 Maamar 7), Magallán 7, Eric 6, Cuadrado 6½, Wendel 5½, Furuhashi 7, Grillitsch 6½, Kevin Macedo 6½ | | Independiente | 1 | 21 Vranckx | | Half-time: | 1-0 | | Referee: | Webb 6½ | | Attendance: | 56,036 | | Possession: | 63%-37% | | Total shots: | 5-14 | | MoM: | Molina | | TV: | live |
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| | (4-3-3): Hugo 6½, Rosier 6, Rojo 7½, Meza 7, Pezzella 7, Ramos Mingo 6, Vecchio 6½, Sottil 5½, Cutrone 7, Vranckx 7, Benedetto 6 | | Benfica | 1 | 49 David |
| | (4-4-2): Chevalier 7, Molina 8½, Hato 7½, Kimmich 7 (61 Doué 7½), Rúben Dias 7 (71 Torres 7), Van De Ven 7½, Palmer 6½, Pedro Neto 7, Samu 7, Vitinha 6½, David 6 | | Milan | 4 | 5 Zaccagni, 20 Jovic, 39 Zaccagni, 43 Zaccagni | | Half-time: | 4-1 | | Referee: | Elton Macaé 10½ | | Attendance: | 47,127 | | Possession: | 51%-49% | | Total shots: | 9-11 | | MoM: | Wijnaldum |
| | 1 Ricci | | (4-3-3): Bulka 6, Kehrer 7, Boscagli 6, Koné 7½, De Vrij 7½, Ely 6, Thauvin 7, Zaccagni 7½, Jovic 7, Ricci 6½, Weiper 6 | | Flamengo | 2 | 16 Reus, 79 Wijnaldum |
| | (4-3-3): Torop 6, Araújo 7, Fran García 6½ (60 Wijnaldum 8½), Danilo 7, Zubeldia 6, Andersen 7, Almiron 7, Reus 7½, Depay 6½, Kanté 6, Galeno 6½ | | Napoli | 4 | 3 Raúl, 20 Sérgio Gómez, 29 Sérgio Gómez, 74 Sérgio Gómez | | Half-time: | 3-1 | | Referee: | Ancion 6 | | Attendance: | 39,656 | | Possession: | 51%-49% | | Total shots: | 11-17 | | MoM: | Cambiaso |
| | 30 Barco | | (4-3-3): Carnesecchi 6, Piris 7½, Cambiaso 8, Kessié 7, Acerbi 7, Řstigĺrd 6½, Zanotti 7, Sérgio Gómez 7, Raúl 5 (76 Fayzullaev 6), Barco 6½, Dembélé 6½ | | Torino | 2 | 45 Verdi, 51 Lukic | | 27 Vojvoda, 59 Mandragora, 77 Djidji | | (4-3-3): Berisha 6, Zappacosta 7, Vojvoda 7, Lukic 7½, Kryvtsov 7½, Djidji 6½, Edera 7, Álex Berenguer 7, Pellegri 6, Mandragora 6½, Verdi 6 | | Palmeiras | 3 | 12 Douglas Santos, 14 Raphael Cavalcante, 42 Philippe Coutinho | | Half-time: | 3-0 | | Referee: | Sarvan 7½ | | Attendance: | 37,916 | | Possession: | 51%-49% | | Total shots: | 17-15 | | MoM: | Joăo Moutinho |
| | 19 Raphael Cavalcante | | (4-3-3): Weverton 7, Tobio 7, Douglas Santos 7½, Joăo Moutinho 7½, Gómez 7½, Rodrigo Becăo 7, Chará 6½, Philippe Coutinho 6½, Deyverson 5½ (48 Vitinho 7), Raphael Cavalcante 7 (80 Papagaio 6), Marquinhos Gabriel 6½ | | Celta Vigo | 0 |
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| | (4-3-3): Adán 7½, Solari 7, Javi Galán 7½, Gueye 7½, David López 7, Llorente 6½, Thiago Galhardo 7½, Swedberg 6½, Miguel Rodríguez 6½, Pineda 6½, Latasa 6 | | Roma | 1 | 17 El Shaarawy | | Half-time: | 1-0 | | Referee: | Cesari 5½ | | Attendance: | 38,641 | | Possession: | 49%-51% | | Total shots: | 13-13 | | MoM: | Bernat |
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| | (4-3-3): Arnau Tenas 6½, Lazzari 6, Perisic 6½ (81 Pirola 6), Mkhitaryan 8, Hancko 6½, Balogh 6½, Volland 6½, El Shaarawy 7, Brescianini 6, Lozano 5½, Ings 7 | | Real Madrid | 1 | 82 Bernat |
| | (4-3-3): Lunin 6½, Nacho 8, Bernat 8, Vecino 7½, Dunk 7, Víctor 7½, Weiser 7½, Peter 7, Rafa Mir 7, Iker Muńoz 6½, Mariano 7 | | Sassuolo | 1 | 22 Matheus | | Half-time: | 1-1 | | Referee: | Marriner 6½ | | Attendance: | 20,353 | | Possession: | 43%-57% | | Total shots: | 8-14 | | MoM: | Ndidi |
| | 47 Tripaldelli, 48 Matheus | | (4-3-3): Muslera 7½, Chiriches 6½, Tripaldelli 7, Ruan 6, Erlic 7, Marlon 6, Rigoni 6½, Boga 6½, Petagna 6½, Matheus 7, Berardi 6½ | | Inter | 1 | 45 Kramaric |
| | (4-3-3): Gollini 7½, Duverne 6, Aké 7½, Ndidi 7½, Denayer 6½, Davis 7½, Orsolini 6½, Kyriakopoulos 7, Vardy 6½, Stengs 7, Kramaric 6½ | | TSG Hoffenheim | 3 | 5 Bruun Larsen, 31 Pedro Porro, 45 Bruun Larsen | | Half-time: | 3-1 | | Referee: | Atkinson 7 | | Attendance: | 45,451 | | Possession: | 48%-52% | | Total shots: | 11-16 | | MoM: | Murphy | | TV: | highlights |
| | 15 Saibari, 90 Rui Silva | | (4-3-3): Rui Silva 6½, Pedro Porro 7½, Wijndal 7, Steijn 7, De Ligt 7, Klostermann 5½ (76 Luiz Gustavo 5½), Francisco Conceiçăo 6, Bruun Larsen 7, Fekir 7, Saibari 7, Kolo-Muani 6½ | | Manchester City | 1 | 36 Lokonga | | 34 Insigne, 41 Lokonga | | (4-3-3): Vlachodimos 6½, Adarabioyo 6, Carrasco 7, Hřjbjerg 7½, Otamendi 6½, Badiashile 6½, Murphy 7½, Diatta 7, Solanke 7, Lokonga 7, Insigne 5½ |
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