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| Round 1 (22) Athletic Bilbao - Osasuna Atlético-MG - Celta Vigo Barcelona - Napoli Manchester City - Torino Milan - Real Madrid Roma - Fiorentina Sampdoria - Bayern München Sassuolo - Lille TSG Hoffenheim - SC Heerenveen Valencia - Palmeiras West Ham United - Independiente | Round 2 (23) Bayern München - Roma Celta Vigo - Barcelona Fiorentina - Sampdoria Independiente - Valencia Lille - TSG Hoffenheim Napoli - Manchester City Osasuna - West Ham United Palmeiras - Milan Real Madrid - Sassuolo SC Heerenveen - Athletic Bilbao Torino - Atlético-MG |
| Round 3 (24) Athletic Bilbao - Lille Atlético-MG - Independiente Barcelona - Fiorentina Manchester City - Real Madrid Milan - Napoli Roma - Palmeiras Sampdoria - Torino Sassuolo - Celta Vigo TSG Hoffenheim - Bayern München Valencia - Osasuna West Ham United - SC Heerenveen | Round 4 (25) Bayern München - Manchester City Celta Vigo - West Ham United Fiorentina - Athletic Bilbao Independiente - TSG Hoffenheim Lille - Valencia Napoli - Roma Osasuna - Sassuolo Palmeiras - Sampdoria Real Madrid - Atlético-MG SC Heerenveen - Milan Torino - Barcelona |
| Round 5 (26) Athletic Bilbao - Napoli Atlético-MG - Osasuna Barcelona - Lille Manchester City - Palmeiras Milan - Independiente Roma - Celta Vigo Sampdoria - Real Madrid Sassuolo - Fiorentina TSG Hoffenheim - Torino Valencia - SC Heerenveen West Ham United - Bayern München | Round 6 (27) Atlético-MG - Valencia Barcelona - Sampdoria Osasuna - Lille Palmeiras - Napoli Real Madrid - Celta Vigo Roma - Manchester City SC Heerenveen - Independiente Sassuolo - Milan TSG Hoffenheim - Fiorentina Torino - Bayern München West Ham United - Athletic Bilbao |
| Round 7 (28) Athletic Bilbao - Atlético-MG Bayern München - Real Madrid Celta Vigo - Palmeiras Fiorentina - Torino Independiente - Osasuna Lille - SC Heerenveen Manchester City - Barcelona Milan - West Ham United Napoli - TSG Hoffenheim Sampdoria - Roma Valencia - Sassuolo | Round 8 (29) Bayern München - Fiorentina Lille - Manchester City Milan - Atlético-MG Napoli - Celta Vigo Palmeiras - Real Madrid Roma - Barcelona SC Heerenveen - Osasuna Sampdoria - Valencia Sassuolo - West Ham United TSG Hoffenheim - Athletic Bilbao Torino - Independiente |
| Round 9 (30) Athletic Bilbao - Roma Atlético-MG - Sassuolo Barcelona - Palmeiras Celta Vigo - Bayern München Fiorentina - SC Heerenveen Independiente - Lille Manchester City - Sampdoria Osasuna - Torino Real Madrid - Napoli Valencia - Milan West Ham United - TSG Hoffenheim | Round 10 (31) Barcelona - Atlético-MG Bayern München - Osasuna Celta Vigo - Independiente Fiorentina - Valencia Manchester City - Sassuolo Napoli - Lille Palmeiras - TSG Hoffenheim Real Madrid - Athletic Bilbao Roma - Milan Sampdoria - West Ham United Torino - SC Heerenveen |
| Round 11 (32) Athletic Bilbao - Palmeiras Atlético-MG - Manchester City Independiente - Real Madrid Lille - Bayern München Milan - Fiorentina Osasuna - Celta Vigo SC Heerenveen - Roma Sassuolo - Torino TSG Hoffenheim - Sampdoria Valencia - Barcelona West Ham United - Napoli | Round 12 (33) Athletic Bilbao - Torino Atlético-MG - Roma Independiente - Palmeiras Lille - Celta Vigo Milan - Bayern München Osasuna - Napoli SC Heerenveen - Sampdoria Sassuolo - Barcelona TSG Hoffenheim - Real Madrid Valencia - Manchester City West Ham United - Fiorentina |
| Round 13 (34) Barcelona - West Ham United Bayern München - Atlético-MG Celta Vigo - Athletic Bilbao Fiorentina - Lille Manchester City - TSG Hoffenheim Napoli - Independiente Palmeiras - Osasuna Real Madrid - SC Heerenveen Roma - Valencia Sampdoria - Sassuolo Torino - Milan | Round 14 (35) Athletic Bilbao - Barcelona Atlético-MG - Napoli Independiente - Sampdoria Lille - Palmeiras Milan - Manchester City Osasuna - Fiorentina SC Heerenveen - Celta Vigo Sassuolo - Bayern München TSG Hoffenheim - Roma Valencia - Torino West Ham United - Real Madrid |
| Round 15 (36) Barcelona - Milan Bayern München - Valencia Celta Vigo - TSG Hoffenheim Fiorentina - Independiente Manchester City - Athletic Bilbao Napoli - SC Heerenveen Palmeiras - West Ham United Real Madrid - Osasuna Roma - Sassuolo Sampdoria - Atlético-MG Torino - Lille | Round 16 (37) Athletic Bilbao - Bayern München Atlético-MG - Fiorentina Independiente - Manchester City Lille - Real Madrid Milan - Sampdoria Osasuna - Roma SC Heerenveen - Palmeiras Sassuolo - Napoli TSG Hoffenheim - Barcelona Valencia - Celta Vigo West Ham United - Torino |
| Round 17 (38) Athletic Bilbao - Independiente Atlético-MG - SC Heerenveen Barcelona - Bayern München Manchester City - Fiorentina Milan - Celta Vigo Roma - Torino Sampdoria - Napoli Sassuolo - Palmeiras TSG Hoffenheim - Osasuna Valencia - Real Madrid West Ham United - Lille | Round 18 (39) Atlético-MG - TSG Hoffenheim Barcelona - Osasuna Bayern München - SC Heerenveen Fiorentina - Palmeiras Manchester City - Celta Vigo Milan - Lille Roma - West Ham United Sampdoria - Athletic Bilbao Sassuolo - Independiente Torino - Real Madrid Valencia - Napoli |
| Round 19 (40) Athletic Bilbao - Valencia Celta Vigo - Sampdoria Independiente - Bayern München Lille - Roma Napoli - Torino Osasuna - Milan Palmeiras - Atlético-MG Real Madrid - Fiorentina SC Heerenveen - Barcelona TSG Hoffenheim - Sassuolo West Ham United - Manchester City | Round 20 (41) Atlético-MG - West Ham United Barcelona - Real Madrid Bayern München - Palmeiras Fiorentina - Napoli Manchester City - Osasuna Milan - Athletic Bilbao Roma - Independiente Sampdoria - Lille Sassuolo - SC Heerenveen Torino - Celta Vigo Valencia - TSG Hoffenheim |
| Round 21 (42) Athletic Bilbao - Sassuolo Celta Vigo - Fiorentina Independiente - Barcelona Lille - Atlético-MG Napoli - Bayern München Osasuna - Sampdoria Palmeiras - Torino Real Madrid - Roma SC Heerenveen - Manchester City TSG Hoffenheim - Milan West Ham United - Valencia | |
| League rounds 22-42 (in brackets) are the respective return ties of rounds 1-21 above, i.e. round 42 is Atlético-MG - Lille, Barcelona - Independiente etc. | |